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• W2112936701 abstract "A general protocol for direct transformation of unreactive C(sp(3))-H bonds to C(sp(3))-CN bonds has been developed. The C-H activation was effected by photoexcited benzophenone, and the generated carbon radical was subsequently trapped with tosyl cyanide to afford the corresponding nitrile in a highly efficient manner. The present methodology is widely applicable to versatile starting materials and, thus, serves as a powerful tool for selective one-carbon elongation for construction of architecturally complex molecules." @default.
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• W2112936701 date "2011-10-12" @default.
• W2112936701 modified "2023-10-18" @default.
• W2112936701 title "Photochemically Induced Radical Transformation of C(sp³)–H Bonds to C(sp³)–CN Bonds" @default.
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• W2112936701 doi "https://doi.org/10.1021/ol202659e" @default.
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