FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2129367003> ?p ?o ?g. }

• W2129367003 endingPage "581" @default.
• W2129367003 startingPage "571" @default.
• W2129367003 abstract "Other| June 01, 1997 Molar volumes of mixing of almandine-pyrope and almandine-spessartine garnets and the crystal chemistry and thermodynamic-mixing properties of the aluminosilicate garnets Charles A. Geiger; Charles A. Geiger Christian-Albrechts-Universitaet zu Kiel, Mineralogisch-Petrographisches Institut, Kiel, Federal Republic of Germany Search for other works by this author on: GSW Google Scholar Anne Feenstra Anne Feenstra Universitaet Bern, Switzerland Search for other works by this author on: GSW Google Scholar American Mineralogist (1997) 82 (5-6): 571–581. https://doi.org/10.2138/am-1997-5-617 Article history first online: 02 Mar 2017 Cite View This Citation Add to Citation Manager Share Icon Share Twitter LinkedIn Tools Icon Tools Get Permissions Search Site Citation Charles A. Geiger, Anne Feenstra; Molar volumes of mixing of almandine-pyrope and almandine-spessartine garnets and the crystal chemistry and thermodynamic-mixing properties of the aluminosilicate garnets. American Mineralogist 1997;; 82 (5-6): 571–581. doi: https://doi.org/10.2138/am-1997-5-617 Download citation file: Ris (Zotero) Refmanager EasyBib Bookends Mendeley Papers EndNote RefWorks BibTex toolbar search Search Dropdown Menu toolbar search search input Search input auto suggest filter your search All ContentBy SocietyAmerican Mineralogist Search Advanced Search Abstract The aluminosilicate garnet binaries almandine-pyrope and almandine-spessartine were studied by powder X-ray and 57Fe Mössbauer methods. Refinements of the unit-cell constants along the almandine-pyrope join show that the volumes of mixing are ideal. Those of the almandine-spessartine join show very small positive deviations from ideality, which can be fitted with a symmetric model having an interaction parameter of WV = 0.24 (±0.05) cm3/mol. Mössbauer spectra recorded at 298 and 77 K show the presence of small amounts of [6]Fe3+, which in the case of almandine-pyrope garnets is also measurable from microprobe analyses. The amount of Fe3+ is generally less than 3.5% of the total Fe for the almandine-pyrope garnets and 1–2% for almandine-spessartine garnets. The molar volumes of mixing of the aluminosilicate garnet binaries are interpreted using a crystal-chemical model involving rigid tetrahedral rotation. The degree of tetrahedral rotation is not linear with increasing size of the divalent X-site cation for the four common aluminosilicate garnet end-members or along the solid solution binary pyrope-grossular. The vibrational entropies of mixing should be positively correlated with the volumes of mixing in the case of garnet, but the masses of the X-site cations must also be considered. The phonon density of states at low energies should show the vibrations of the weakly bonded divalent cations and rigid-unit modes related to tetrahedral rotation. Positive excess vibrational entropies of mixing along a binary could result from increased amplitudes and lower frequencies of vibration of the smaller of the two X-site cations substituting within larger and more distorted dodecahedral sites, as compared to the X site in the smaller volume end-member. This content is PDF only. Please click on the PDF icon to access. First Page Preview Close Modal You do not have access to this content, please speak to your institutional administrator if you feel you should have access." @default.
• W2129367003 created "2016-06-24" @default.
• W2129367003 creator A5017992780 @default.
• W2129367003 creator A5059565203 @default.
• W2129367003 date "1997-06-01" @default.
• W2129367003 modified "2023-09-27" @default.
• W2129367003 title "Molar volumes of mixing of almandine-pyrope and almandine-spessartine garnets and the crystal chemistry and thermodynamic-mixing properties of the aluminosilicate garnets" @default.
• W2129367003 cites W1872226187 @default.
• W2129367003 cites W1965488207 @default.
• W2129367003 cites W1972669079 @default.
• W2129367003 cites W1978188529 @default.
• W2129367003 cites W1984684994 @default.
• W2129367003 cites W1988605025 @default.
• W2129367003 cites W1994816727 @default.
• W2129367003 cites W1999725413 @default.
• W2129367003 cites W2012696244 @default.
• W2129367003 cites W2014115207 @default.
• W2129367003 cites W2042848996 @default.
• W2129367003 cites W2053479702 @default.
• W2129367003 cites W2063909059 @default.
• W2129367003 cites W2102003398 @default.
• W2129367003 cites W2121688201 @default.
• W2129367003 cites W2128197379 @default.
• W2129367003 cites W2155044034 @default.
• W2129367003 cites W2167590372 @default.
• W2129367003 cites W2316447534 @default.
• W2129367003 cites W2324907227 @default.
• W2129367003 cites W2328557404 @default.
• W2129367003 cites W2339199286 @default.
• W2129367003 cites W2339716613 @default.
• W2129367003 cites W2342943161 @default.
• W2129367003 cites W2355690456 @default.
• W2129367003 cites W2399828393 @default.
• W2129367003 cites W2555031893 @default.
• W2129367003 cites W2588432441 @default.
• W2129367003 cites W2591220804 @default.
• W2129367003 cites W3157650310 @default.
• W2129367003 doi "https://doi.org/10.2138/am-1997-5-617" @default.
• W2129367003 hasPublicationYear "1997" @default.
• W2129367003 type Work @default.
• W2129367003 sameAs 2129367003 @default.
• W2129367003 citedByCount "51" @default.
• W2129367003 countsByYear W21293670032012 @default.
• W2129367003 countsByYear W21293670032013 @default.
• W2129367003 countsByYear W21293670032014 @default.
• W2129367003 countsByYear W21293670032015 @default.
• W2129367003 countsByYear W21293670032016 @default.
• W2129367003 countsByYear W21293670032017 @default.
• W2129367003 countsByYear W21293670032019 @default.
• W2129367003 countsByYear W21293670032020 @default.
• W2129367003 countsByYear W21293670032021 @default.
• W2129367003 countsByYear W21293670032022 @default.
• W2129367003 countsByYear W21293670032023 @default.
• W2129367003 crossrefType "journal-article" @default.
• W2129367003 hasAuthorship W2129367003A5017992780 @default.
• W2129367003 hasAuthorship W2129367003A5059565203 @default.
• W2129367003 hasConcept C121332964 @default.
• W2129367003 hasConcept C138777275 @default.
• W2129367003 hasConcept C161790260 @default.
• W2129367003 hasConcept C178790620 @default.
• W2129367003 hasConcept C185592680 @default.
• W2129367003 hasConcept C191897082 @default.
• W2129367003 hasConcept C192562407 @default.
• W2129367003 hasConcept C199289684 @default.
• W2129367003 hasConcept C2779870107 @default.
• W2129367003 hasConcept C2781374366 @default.
• W2129367003 hasConcept C62520636 @default.
• W2129367003 hasConcept C76349523 @default.
• W2129367003 hasConcept C85704489 @default.
• W2129367003 hasConceptScore W2129367003C121332964 @default.
• W2129367003 hasConceptScore W2129367003C138777275 @default.
• W2129367003 hasConceptScore W2129367003C161790260 @default.
• W2129367003 hasConceptScore W2129367003C178790620 @default.
• W2129367003 hasConceptScore W2129367003C185592680 @default.
• W2129367003 hasConceptScore W2129367003C191897082 @default.
• W2129367003 hasConceptScore W2129367003C192562407 @default.
• W2129367003 hasConceptScore W2129367003C199289684 @default.
• W2129367003 hasConceptScore W2129367003C2779870107 @default.
• W2129367003 hasConceptScore W2129367003C2781374366 @default.
• W2129367003 hasConceptScore W2129367003C62520636 @default.
• W2129367003 hasConceptScore W2129367003C76349523 @default.
• W2129367003 hasConceptScore W2129367003C85704489 @default.
• W2129367003 hasIssue "5-6" @default.
• W2129367003 hasLocation W21293670031 @default.
• W2129367003 hasOpenAccess W2129367003 @default.
• W2129367003 hasPrimaryLocation W21293670031 @default.
• W2129367003 hasRelatedWork W1665186240 @default.
• W2129367003 hasRelatedWork W1963635776 @default.
• W2129367003 hasRelatedWork W1982986772 @default.
• W2129367003 hasRelatedWork W1999234485 @default.
• W2129367003 hasRelatedWork W2009428233 @default.
• W2129367003 hasRelatedWork W2048668849 @default.
• W2129367003 hasRelatedWork W2912648262 @default.
• W2129367003 hasRelatedWork W3082186242 @default.
• W2129367003 hasRelatedWork W3112873639 @default.
• W2129367003 hasRelatedWork W816635825 @default.
• W2129367003 hasVolume "82" @default.
• W2129367003 isParatext "false" @default.

• next