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- W2137029191 endingPage "2040" @default.
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- W2137029191 abstract "A novel reactive phosphorus-containing monomer [1-oxo-2,6,7-trioxa-1- phosphabicyclo-[2.2.2]octane-methyl diallyl phosphate, PDAP] was synthesized, and various amounts of PDAP were combined with unsaturated polyester by radical bulk polymerization. The resulting flame-retardant unsaturated polyester resin (FR-UPR) samples were investigated by thermogravimetric analysis (TGA), microscale combustion calorimetry (MCC), and limiting oxygen index (LOI) tests. Due to the relatively high phosphorus content of PDAP (18.2 wt%), incorporation of this monomer into unsaturated polyester resin (UPR) led to a marked decrease in the heat release capacity (HRC), the total heat release (THR), an increase in the LOI and the char yield upon combustion. In order to elaborate the interactions between the UPR and PDAP in degradation, differences between the experimental and theoretical mass losses of a FR-UPR sample were evaluated. Furthermore, thermogravimetry-Fourier transform infrared (TG-FTIR) and real-time Fourier transform infrared (RTIR) spectroscopy were employed to investigate the degradation behavior of UPRs, providing insight into the degradation mechanism." @default.
- W2137029191 created "2016-06-24" @default.
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- W2137029191 date "2013-10-01" @default.
- W2137029191 modified "2023-09-24" @default.
- W2137029191 title "Unsaturated polyester resins modified with phosphorus-containing groups: Effects on thermal properties and flammability" @default.
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- W2137029191 doi "https://doi.org/10.1016/j.polymdegradstab.2013.07.008" @default.
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