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- W2148889291 abstract "A novel dinuclear zirconium sandwich-type silicotungstate cluster of [(gamma-SiW(10)O(36))(2)Zr(2)(mu-OH)(2)](10-) (1) was synthesized by the reaction of a divacant lacunary gamma-Keggin silicotungstate [gamma-SiW(10)O(36)](8-) with ZrOCl(2).8H(2)O. The anion consisted of two [gamma-SiW(10)O(36)](8-) units sandwiching a diamond Zr(2)(mu-OH)(2) core, and each zirconium atom in 1 was six-coordinated to two mu-OH ligands and four oxygen atoms of two [gamma-SiW(10)O(36)](8-) units. The Zr(2)(mu-OH)(2) core in 1 reacted with methanol to give the corresponding monomethoxo derivative [(gamma-SiW(10)O(36))(2)Zr(2)(mu-OH)(mu-OCH(3))](10-) (2)." @default.
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- W2148889291 date "2007-09-19" @default.
- W2148889291 modified "2023-10-01" @default.
- W2148889291 title "Synthesis and Structural Characterization of a γ-Keggin-Type Dimeric Silicotungstate with a Bis(<i>μ</i>-hydroxo) Dizirconium Core [(γ-SiW<sub>10</sub>O<sub>36</sub>)<sub>2</sub>Zr<sub>2</sub>(<i>μ</i>-OH)<sub>2</sub>]<sup>10</sup><sup>-</sup>" @default.
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- W2148889291 doi "https://doi.org/10.1021/ic701488s" @default.
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