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• W2180713634 abstract "The novel generation and cycloaddition of azomethine ylides from an α-(trimethylsilyl)imine using (polyfluoro)silanes is described. The method was successfully applied to an efficient one-pot process. Namely, an azaallyl anion, generated by abstraction of the hydrogen α to an imino nitrogen, was treated with a di- or trifluorosilane to give an azomethine ylide intermediate below room temperature. The generated 1,3-dipole was smoothly trapped with dipolarophiles to afford nitrogen-containing five-membered heterocycles in good yields." @default.
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• W2180713634 date "2003-02-01" @default.
• W2180713634 modified "2023-09-23" @default.
• W2180713634 title "(Polyfluoro)silane-mediated generation of azomethine ylides from imines and their cycloaddition leading to N-heterocycles" @default.
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• W2180713634 doi "https://doi.org/10.1016/s0040-4039(03)00011-x" @default.
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