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• W2254004876 abstract "The finding of the periodic law is a milestone in chemical science. The periodicity of light elements in the Periodic Table is fully accounted for by quantum mechanics. Here we report that relativistic effects change the bond multiplicity of the group 6 diatomic molecules M2 (M = Cr, Mo, W, Sg) from hextuple bonds for Cr2, Mo2, W2 to quadruple bonds for Sg2, thus breaking the periodicity in the nonrelativistic domain. The same trend is also found for other superheavy-element diatomics Rf2, Db2, Bh2, and Hs2." @default.
• W2254004876 created "2016-06-24" @default.
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• W2254004876 date "2016-01-22" @default.
• W2254004876 modified "2023-10-18" @default.
• W2254004876 title "Relativistic Effects Break Periodicity in Group 6 Diatomic Molecules" @default.
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• W2254004876 doi "https://doi.org/10.1021/jacs.5b11793" @default.
• W2254004876 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26787134" @default.
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