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- W2296483670 abstract "The stereoselectivity in the 6-exo cyclization of α-carbamoyl radicals was investigated experimentally and theoretically. The BEt3/O2-initiated iodine-atom-transfer radical cyclization reactions of substituted N-(but-3-en-1-yl)-N-(tert-butyl)-2-iodoalkanamides were carried out, which led to the predominant formations of 3,4-cis, 4,5-trans, or 4,6-trans substituted δ-lactams. Density functional calculations at the B3LYP/6-31G* level revealed that the 6-exo radical cyclization proceeds via boat-conformational transition states. Furthermore, a mechanistic insight into the stereoselectivity was provided and the calculation results were in excellent agreement with the experimental observations." @default.
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- W2296483670 date "2016-03-07" @default.
- W2296483670 modified "2023-10-16" @default.
- W2296483670 title "Stereoselectivity of 6-<i>Exo</i> Cyclization of α-Carbamoyl Radicals" @default.
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- W2296483670 doi "https://doi.org/10.1021/acs.joc.6b00008" @default.
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