Matches in SemOpenAlex for { <https://semopenalex.org/work/W2308371012> ?p ?o ?g. }
- W2308371012 endingPage "2929" @default.
- W2308371012 startingPage "2923" @default.
- W2308371012 abstract "Here we report a mechanism study of the hydrogenation of bicarbonate by tetradentate phosphines iron-complexes. It is an extension of our recent study on the reverse reaction by the same type of complexes [Chem.-Eur. J. 2013, 19, 11869], with special emphasis herein on the effects of the choice of solvent. By using density functional theory we have located the most plausible mechanism and have found remarkable effects of the solvent on the reversibility of this reaction. We predict that the solvent used in experiment, MeOH, for the hydrogenation of bicarbonate to formate could be replaced to enhance the activity of the system. There is a direct correlation of the solubility of the base to favor or disfavor the hydrogenation of bicarbonate to formate." @default.
- W2308371012 created "2016-06-24" @default.
- W2308371012 creator A5006624945 @default.
- W2308371012 creator A5023997633 @default.
- W2308371012 creator A5041553126 @default.
- W2308371012 creator A5047606277 @default.
- W2308371012 date "2016-04-07" @default.
- W2308371012 modified "2023-10-16" @default.
- W2308371012 title "Bicarbonate Hydrogenation Catalyzed by Iron: How the Choice of Solvent Can Reverse the Reaction" @default.
- W2308371012 cites W1966182479 @default.
- W2308371012 cites W1975506590 @default.
- W2308371012 cites W1975904524 @default.
- W2308371012 cites W1978514689 @default.
- W2308371012 cites W1979845823 @default.
- W2308371012 cites W1987528061 @default.
- W2308371012 cites W1988674631 @default.
- W2308371012 cites W1989723874 @default.
- W2308371012 cites W1989790338 @default.
- W2308371012 cites W1994565612 @default.
- W2308371012 cites W1995279701 @default.
- W2308371012 cites W1999086206 @default.
- W2308371012 cites W2008475487 @default.
- W2308371012 cites W2008872937 @default.
- W2308371012 cites W2020078456 @default.
- W2308371012 cites W2020561818 @default.
- W2308371012 cites W2023072678 @default.
- W2308371012 cites W2025437593 @default.
- W2308371012 cites W2030795020 @default.
- W2308371012 cites W2033182196 @default.
- W2308371012 cites W2042926180 @default.
- W2308371012 cites W2043044707 @default.
- W2308371012 cites W2049083623 @default.
- W2308371012 cites W2050035612 @default.
- W2308371012 cites W2053717925 @default.
- W2308371012 cites W2073637781 @default.
- W2308371012 cites W2074463764 @default.
- W2308371012 cites W2078277035 @default.
- W2308371012 cites W2080766536 @default.
- W2308371012 cites W2081890623 @default.
- W2308371012 cites W2084442872 @default.
- W2308371012 cites W2086957099 @default.
- W2308371012 cites W2087081982 @default.
- W2308371012 cites W2091284822 @default.
- W2308371012 cites W2092802361 @default.
- W2308371012 cites W2092993934 @default.
- W2308371012 cites W2093290700 @default.
- W2308371012 cites W2100546796 @default.
- W2308371012 cites W2103017255 @default.
- W2308371012 cites W2106985053 @default.
- W2308371012 cites W2108735359 @default.
- W2308371012 cites W2109687367 @default.
- W2308371012 cites W2109816957 @default.
- W2308371012 cites W2110154495 @default.
- W2308371012 cites W2110659651 @default.
- W2308371012 cites W2121757724 @default.
- W2308371012 cites W2123938655 @default.
- W2308371012 cites W2125547286 @default.
- W2308371012 cites W2125653280 @default.
- W2308371012 cites W2125845584 @default.
- W2308371012 cites W2135072167 @default.
- W2308371012 cites W2136808884 @default.
- W2308371012 cites W2142527379 @default.
- W2308371012 cites W2144480018 @default.
- W2308371012 cites W2150697053 @default.
- W2308371012 cites W2171836549 @default.
- W2308371012 cites W2258795475 @default.
- W2308371012 cites W2302014605 @default.
- W2308371012 cites W2307729779 @default.
- W2308371012 cites W2332611934 @default.
- W2308371012 cites W2362690370 @default.
- W2308371012 cites W2424496277 @default.
- W2308371012 cites W3105938624 @default.
- W2308371012 cites W3206606417 @default.
- W2308371012 cites W4247513064 @default.
- W2308371012 cites W4256059966 @default.
- W2308371012 doi "https://doi.org/10.1021/acscatal.6b00071" @default.
- W2308371012 hasPublicationYear "2016" @default.
- W2308371012 type Work @default.
- W2308371012 sameAs 2308371012 @default.
- W2308371012 citedByCount "28" @default.
- W2308371012 countsByYear W23083710122016 @default.
- W2308371012 countsByYear W23083710122017 @default.
- W2308371012 countsByYear W23083710122018 @default.
- W2308371012 countsByYear W23083710122019 @default.
- W2308371012 countsByYear W23083710122020 @default.
- W2308371012 countsByYear W23083710122021 @default.
- W2308371012 countsByYear W23083710122022 @default.
- W2308371012 countsByYear W23083710122023 @default.
- W2308371012 crossrefType "journal-article" @default.
- W2308371012 hasAuthorship W2308371012A5006624945 @default.
- W2308371012 hasAuthorship W2308371012A5023997633 @default.
- W2308371012 hasAuthorship W2308371012A5041553126 @default.
- W2308371012 hasAuthorship W2308371012A5047606277 @default.
- W2308371012 hasConcept C132439834 @default.
- W2308371012 hasConcept C134306372 @default.
- W2308371012 hasConcept C155574463 @default.
- W2308371012 hasConcept C161790260 @default.
- W2308371012 hasConcept C178790620 @default.