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- W2318892038 startingPage "7809" @default.
- W2318892038 abstract "Rate coefficients for the reaction of OH radical with eleven C3−C6 hydroxyalkyl nitrates and with two C4 hydroxy nitrates containing a double bond were determined at atmospheric pressure and 296 ± 2 K. The rate coefficients were measured in a photochemical reactor by the relative rate technique, employing solid-phase microextraction (SPME) coupled to gas chromatography (GC) for detection of the organic reactants. Hydroxyalkyl nitrates react faster than alkyl nitrates with the OH radical. The rate coefficients increase with increasing chain length and separation between the hydroxy and the nitrooxy groups. By including different loss processes such as photolysis, gas-phase reactions, and solubility, the tropospheric lifetime of C3−C6 hydroxyalkyl nitrates is estimated to range between 0.5 and 4.5 days. Due to their higher reactivity and solubility, hydroxyalkyl nitrates have a shorter atmospheric lifetime than alkyl nitrates." @default.
- W2318892038 created "2016-06-24" @default.
- W2318892038 creator A5030220859 @default.
- W2318892038 creator A5066556450 @default.
- W2318892038 date "2003-09-06" @default.
- W2318892038 modified "2023-10-03" @default.
- W2318892038 title "The Atmospheric Fate of C<sub>3</sub>−C<sub>6</sub> Hydroxyalkyl Nitrates" @default.
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- W2318892038 doi "https://doi.org/10.1021/jp035064l" @default.
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