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• W2324867239 abstract "Three novel uranyl(VI) peroxide complexes, [(UO2)2(CH3COO)2(O2)(C10H8N2)] (1), [(UO2)2(CH3COO)2(O2)(C12H12N2)] (2), and [(UO2)3(CH3COO)4(O2)(C15H11N3)2] (3), have been synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, and luminescence spectroscopy. Each of these structures feature a [(UO2)2(O2)] dimer with additional coordination by acetate, 2,2′-bipyridine (BPY), 5,5′-dimethyl-2,2′-bipyridine (MeBPY), or 2,2′:6,2″-terpyridine (TPY). Compound 3 consists of an additional uranyl unit functionalized with a TPY donor ligand. The presence of the peroxo ligand in 1–3 is due to in situ generation of peroxide when preparative solutions of 1–3 were exposed to ambient light and/or sunlight." @default.
• W2324867239 created "2016-06-24" @default.
• W2324867239 creator A5038490788 @default.
• W2324867239 creator A5066308384 @default.
• W2324867239 date "2015-04-15" @default.
• W2324867239 modified "2023-09-24" @default.
• W2324867239 title "Uranyl-Promoted Peroxide Generation: Synthesis and Characterization of Three Uranyl Peroxo [(UO₂)₂(O₂)] Complexes" @default.
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• W2324867239 doi "https://doi.org/10.1021/ic502767k" @default.
• W2324867239 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25875867" @default.
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