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• W2330751567 endingPage "5510" @default.
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• W2330751567 abstract "Dinuclear Pt−Si complexes, [(Ph3P)Pt(μ-η2-H−SiHAr)]2 (Ar = 2-isopropyl-6-methylphenyl (IMP), 2,4,6-trimethoxyphenyl (TMP), 2,4,6-trimethylphenyl (Mes), pentaphenylphenyl (PPP), 2,4,6-tris(trifluoromethyl)phenyl (RF)) have been synthesized from the reaction of ArSiH3 with (Ph3P)2Pt(η2-C2H4). These complexes were characterized by multinuclear NMR and IR spectroscopy and X-ray crystallography (PPP and RF systems). The dinuclear complexes contain a 3c−2e nonclassical interaction for Pt···H···Si, which is supported by spectroscopic and crystallographic data. Both cis and trans isomers are formed when Ar = IMP, TMP, Mes, and these complexes are fluxional on the NMR time scale. Only the trans isomer is generated with Ar = PPP, RF. These complexes exhibit an unusual low-field 1H NMR resonance for the terminal Si−H and an upfield shift for the bridging hydride. X-ray crystallographic analysis of the PPP and RF systems (also previous results for IMP) reveal two different Si−Pt distances, with the longer distance corresponding to the Pt···H···Si interaction." @default.
• W2330751567 created "2016-06-24" @default.
• W2330751567 creator A5005804367 @default.
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• W2330751567 date "2000-11-11" @default.
• W2330751567 modified "2023-09-28" @default.
• W2330751567 title "Synthesis and Characterization of Diplatinum Complexes Containing Bridging μ-η²-H−SiHAr Ligands. X-ray Crystal Structure Determination of {(Ph₃P)Pt[μ-η²-H−SiHAr]}₂ (Ar = 2,4,6-(CF₃)₃C₆H₂, C₆Ph₅)" @default.
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• W2330751567 doi "https://doi.org/10.1021/om000602r" @default.
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