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• W2338498265 endingPage "1644" @default.
• W2338498265 startingPage "1637" @default.
• W2338498265 abstract "ABSTRACT Photoresponsive molecularly imprinted nanocavities were prepared using a newly designed functional monomer bearing a photoresponsive spiropyran moiety with a carboxy group that can interact with atrazine (the template molecule), in which the spiropyran moiety was incorporated into the binding cavities. Spectrophotometric analysis confirmed that the spiropyran moiety was photoresponsive even after polymerization. The selectivity of the EDMA‐based molecularly imprinted polymer (MIP EDMA ) was tested to examine the binding behavior of atrazine and other agrochemicals, revealing that the atrazine‐imprinted polymer can bind selectively to triazine herbicides. Photo‐triggered switching of the binding activity in MIP EDMA was investigated, and the binding activity was found to decrease dramatically after UV light irradiation, suggesting that the spiropyran moiety in the binding cavities was transformed to the merocyanine form, resulting in unfavorable translocation of the carboxy group for atrazine binding. Consequently, the spiropyran‐based MIP EDMA demonstrated in this study could open a way to realizing reliable photoresponsive smart materials. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54 , 1637–1644" @default.
• W2338498265 created "2016-06-24" @default.
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• W2338498265 date "2016-04-21" @default.
• W2338498265 modified "2023-10-05" @default.
• W2338498265 title "Molecularly imprinted polymers bearing spiropyran-based photoresponsive binding sites capable of photo-triggered switching for molecular recognition activity" @default.
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• W2338498265 doi "https://doi.org/10.1002/polb.24066" @default.
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