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- W2419492078 abstract "It is a big challenge to develop fluorescent probes for selective detection of DNA with specific sequences in aqueous buffers. We report a new tetraphenylethene-based Zn(2+)-cyclen complex (TPECyZn), and a chemo-sensing ensemble of the Zn complex with phenol red. TPECyZn showed significant fluorescence enhancement upon binding to thymine-rich DNA in HEPES buffers. But its selectivity was not high enough to eliminate the interference from some random DNA. By constructing the chemo-sensing ensemble of TPECyZn with phenol red, the background fluorescence was eliminated due to the energy transfer from TPECyZn to phenol red. Moreover, this chemo-sensing ensemble revealed high selectivity in detecting thymine-rich single-stranded DNA over other DNA in aqueous buffer. It can detect poly deoxythymidylic acid sequence as short as 2 nt. This detection in aqueous media makes this probe feasible in real application." @default.
- W2419492078 created "2016-06-24" @default.
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- W2419492078 date "2016-11-01" @default.
- W2419492078 modified "2023-09-23" @default.
- W2419492078 title "Zn2+-cyclen-based complex enable a selective detection of single-stranded thymine-rich DNA in aqueous buffer" @default.
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- W2419492078 doi "https://doi.org/10.1016/j.bios.2016.05.085" @default.
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