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• W2519658889 abstract "Reaction of Ce(NO3)3(THF)4 with Li3(THF)3(NN′3) (NN′3 = N(CH2CH2NR)3, R = SitBuMe2) in Et2O, in the presence of 12-crown-4, results in the formation of [Li(12-crown-4)][(NN′3)Ce(O)] (1) in 36% yield. This transformation proceeds via formation of a Ce(III) nitrate intermediate, [Li(12-crown-4)][(NN′3)Ce(κ2-O2NO)] (2), which undergoes inner sphere nitrate reduction. In addition, reaction of 1 with tBuMe2SiCl results in the formation of (NN′3)Ce(OSitBuMe2) (3), confirming the nucleophilic character of its oxo ligand. Natural bond orbital and quantum theory of atoms-in-molecules data reveal the Ce–O interaction in 1 to be significantly covalent, and strikingly similar to analogous U–O bonding." @default.
• W2519658889 created "2016-09-23" @default.
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• W2519658889 date "2016-09-20" @default.
• W2519658889 modified "2023-10-01" @default.
• W2519658889 title "Formation of a Ce(IV) Oxo Complex via Inner Sphere Nitrate Reduction" @default.
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• W2519658889 doi "https://doi.org/10.1021/jacs.6b07932" @default.
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