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• W2560322562 abstract "Abstract To investigate the effect of Ba 2+ and Co 2+ substitution on the multiferroic properties of the BiFeO 3 (BFO) ceramic, Bi 1-x Ba x Fe 1-y Co y O 3 (x = 0,y = 0 and x = 0.2, y = 0,0.015,0.03,0.04,0.05) ceramics were prepared using sol-gel method. Multiferroic properties of BFO have been improved considerably on Ba 2+ and Co 2+ substitution at Bi and Fe site, respectively. Full pattern fitting of the XRD profile pattern confirmed the structural transition from rhombohedral to pseudo-cubic phase. The magnetisation in BFO rises appreciably and found to be 0.463 emu/g for Bi 1-x Ba x Fe 1-y Co y O 3 (x = 0.2, y = 0.05) ceramic nanoparticles. The abrupt increase in magnetization for Bi 0.8 Ba 0.2 Fe 0.95 Co 0.05 O 3 is due to anti-ferromagnetic orbital ordering among Fe/Co ions. The orbital ordering among the ions would change the low spin state of the Co 2+ ions to high spin state and results in increased magnetization. Beside, the Co substitution is found helpful in reducing the coercivity of the magnetic nanoparticles for their application as magnetic sensors. The Ferroelectric behavior of Ba and Co substituted samples revealed that increase in maximum polarization with increasing Co content is due to interactions among different Jahn-Teller active Co 2+ ions. Moreover, the slimmer polarization-electric field (P-E) loops on increasing Co content implying the relaxor ferroelectric behavior of the samples." @default.
• W2560322562 created "2016-12-16" @default.
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• W2560322562 date "2017-03-01" @default.
• W2560322562 modified "2023-09-27" @default.
• W2560322562 title "Structural transitions and multiferrocity in Ba and Co substituted nanosized bismuth ferrite" @default.
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• W2560322562 doi "https://doi.org/10.1016/j.jallcom.2016.12.082" @default.
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