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- W2620492022 abstract "Abstract The reaction between vanadyl sulfate and an NNO donor Schiff base (HL1 or HL2) in methanol resulted in the formation of two new binuclear vanadium(V) complexes, viz., [(L1)VO(μ-O)2VO(L1)]0.5H2O (1) and [(L2)VO(μ-O)2VO(L2)] (2) (L1 = N′-[(E)-phenyl(pyridin-2-yl)methylidene]benzohydrazide and L2 = N′-[(E)-phenyl(pyridin-2-yl)methylidene]furan-2-carbohydrazide). During the reaction, atmospheric oxygen spontaneously acted as an oxidizing agent and yielded new (VIV → VV) vanadium(V) complexes. The electronic spectra of 1 and 2 shown the vanadium(V) centre is in a distorted octahedral environment in each case. The complexes were characterized by routine physico-chemical methods. The single crystal X-ray structures of 1 and 2 also revealed a distorted octahedral coordination around each of the vanadium(V) centres, confirming the NNO binding mode of the ligands L1 and L2. In these binuclear complexes, the bridging functions are the μ-oxido bonds. The occurrence of weak CH⋯π interactions in 1 and π⋯π stacking interactions in 2 contribute extra stabilization in their solid state. The complexes catalyzed the dismutation of superoxide in an alkaline nitroblue tetrazolium chloride assay and the IC50 values were estimated." @default.
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- W2620492022 date "2017-09-01" @default.
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- W2620492022 title "New di-μ-oxidovanadium(V) complexes with NNO donor Schiff bases: Synthesis, crystal structures and electrochemical studies" @default.
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- W2620492022 doi "https://doi.org/10.1016/j.poly.2017.05.028" @default.
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