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- W2783641514 abstract "It has been established that a cationic rhodium(I)/(R)-BINAP complex catalyzes the asymmetric [2 + 2 + 2] cycloaddition of unsymmetrical α,ω-diynes with acenaphthylene at room temperature to give the corresponding chiral multicyclic compounds with high yields and ee values. Interestingly, enantioselectivity highly depended on the structures of α,ω-diynes used. The structural requirements of α,ω-diynes for high enantioselectivity were opposite to those in our previously reported cationic rhodium(I)/(R)-Difluorphos complex-catalyzed asymmetric [2 + 2 + 2] cycloaddition of α,ω-diynes with indene." @default.
- W2783641514 created "2018-01-26" @default.
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- W2783641514 date "2018-02-01" @default.
- W2783641514 modified "2023-10-15" @default.
- W2783641514 title "Rhodium-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of Unsymmetrical α,ω-Diynes with Acenaphthylene" @default.
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- W2783641514 doi "https://doi.org/10.1021/acs.joc.7b03042" @default.
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