Matches in SemOpenAlex for { <https://semopenalex.org/work/W2790577906> ?p ?o ?g. }
- W2790577906 endingPage "7032" @default.
- W2790577906 startingPage "7026" @default.
- W2790577906 abstract "Abstract Brønsted acids and protic solvents mediate acyl transfer, known as the Mumm rearrangement, from imidates to the corresponding acylamides. This represents a key step in several reactions, for example, the Ugi four‐component reaction (U‐4CR) and Passerini three‐component reaction (P‐3CR). Herein, an unprecedented break of the non‐reversibility of the Mumm rearrangement is reported. A combination of electrospray tandem mass spectrometry (ESI‐MS/MS), infrared multiphoton dissociation (IRMPD) ion spectroscopy and theoretical calculations demonstrates the occurrence of the retro‐Mumm rearrangement of protonated isopeptides in the gas phase. In the gas phase, the extra proton acquired during ESI promotes the backward isomerisation reaction in a catalytic fashion." @default.
- W2790577906 created "2018-03-29" @default.
- W2790577906 creator A5034934143 @default.
- W2790577906 creator A5035026621 @default.
- W2790577906 creator A5062118531 @default.
- W2790577906 creator A5065601226 @default.
- W2790577906 creator A5068455024 @default.
- W2790577906 creator A5076856813 @default.
- W2790577906 date "2018-04-26" @default.
- W2790577906 modified "2023-09-27" @default.
- W2790577906 title "An Unprecedented Retro-Mumm Rearrangement Revealed by ESI-MS/MS, IRMPD Spectroscopy, and DFT Calculations" @default.
- W2790577906 cites W1484962446 @default.
- W2790577906 cites W1555590297 @default.
- W2790577906 cites W1967268494 @default.
- W2790577906 cites W1973682902 @default.
- W2790577906 cites W1974415226 @default.
- W2790577906 cites W1982037960 @default.
- W2790577906 cites W1982356449 @default.
- W2790577906 cites W1985973605 @default.
- W2790577906 cites W1986576432 @default.
- W2790577906 cites W1996925118 @default.
- W2790577906 cites W1998867917 @default.
- W2790577906 cites W2000798961 @default.
- W2790577906 cites W2000913999 @default.
- W2790577906 cites W2011974256 @default.
- W2790577906 cites W2023271753 @default.
- W2790577906 cites W2023825272 @default.
- W2790577906 cites W2026363806 @default.
- W2790577906 cites W2031591152 @default.
- W2790577906 cites W2036888928 @default.
- W2790577906 cites W2044571906 @default.
- W2790577906 cites W2051223292 @default.
- W2790577906 cites W2055722474 @default.
- W2790577906 cites W2056836040 @default.
- W2790577906 cites W2057090139 @default.
- W2790577906 cites W2059091788 @default.
- W2790577906 cites W2061817534 @default.
- W2790577906 cites W2062100561 @default.
- W2790577906 cites W2063651965 @default.
- W2790577906 cites W2065393153 @default.
- W2790577906 cites W2068593768 @default.
- W2790577906 cites W2069279756 @default.
- W2790577906 cites W2072753787 @default.
- W2790577906 cites W2073401456 @default.
- W2790577906 cites W2074717965 @default.
- W2790577906 cites W2098162412 @default.
- W2790577906 cites W2099421650 @default.
- W2790577906 cites W2107654249 @default.
- W2790577906 cites W2108967153 @default.
- W2790577906 cites W2110299201 @default.
- W2790577906 cites W2111132765 @default.
- W2790577906 cites W2130722140 @default.
- W2790577906 cites W2134498998 @default.
- W2790577906 cites W2148284063 @default.
- W2790577906 cites W2149411464 @default.
- W2790577906 cites W2158052539 @default.
- W2790577906 cites W2169372371 @default.
- W2790577906 cites W2171688487 @default.
- W2790577906 cites W2179382838 @default.
- W2790577906 cites W2229701663 @default.
- W2790577906 cites W2266075419 @default.
- W2790577906 cites W2284486775 @default.
- W2790577906 cites W2291536210 @default.
- W2790577906 cites W2294786061 @default.
- W2790577906 cites W2298949947 @default.
- W2790577906 cites W2312292995 @default.
- W2790577906 cites W2325016811 @default.
- W2790577906 cites W2331521712 @default.
- W2790577906 cites W2331948266 @default.
- W2790577906 cites W2335025434 @default.
- W2790577906 cites W2405970225 @default.
- W2790577906 cites W2416179333 @default.
- W2790577906 cites W2507151448 @default.
- W2790577906 cites W2508084195 @default.
- W2790577906 cites W2517780983 @default.
- W2790577906 cites W2557163331 @default.
- W2790577906 cites W2582539534 @default.
- W2790577906 cites W2588201076 @default.
- W2790577906 cites W2592495937 @default.
- W2790577906 cites W2614856474 @default.
- W2790577906 cites W2623874475 @default.
- W2790577906 cites W2756075208 @default.
- W2790577906 cites W4233362247 @default.
- W2790577906 cites W4235547089 @default.
- W2790577906 cites W4245447309 @default.
- W2790577906 cites W4245851692 @default.
- W2790577906 cites W4251451046 @default.
- W2790577906 doi "https://doi.org/10.1002/chem.201800347" @default.
- W2790577906 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29517821" @default.
- W2790577906 hasPublicationYear "2018" @default.
- W2790577906 type Work @default.
- W2790577906 sameAs 2790577906 @default.
- W2790577906 citedByCount "14" @default.
- W2790577906 countsByYear W27905779062018 @default.
- W2790577906 countsByYear W27905779062019 @default.
- W2790577906 countsByYear W27905779062020 @default.
- W2790577906 countsByYear W27905779062021 @default.
- W2790577906 countsByYear W27905779062022 @default.