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• W2790976720 abstract "In this work, the phase behavior for a binary and ternary mixture of polymer with a tetrahydrofurfuryl acrylate (THFA) repeating unit in supercritical conditions were investigated experimentally and theoretically. High-pressure solubility data for the THFA in supercritical carbon dioxide (CO2) fluid were presented over a broad temperature range from 313.2 K to 393.2 K and up to a pressure of 21.86 MPa. The cloud-point measurements in binary and ternary mixtures for poly(tetrahydrofurfuryl acrylate) [PTHFA] + THFA or dimethyl ether (DME) in supercritical CO2 were carried out up to 456.2 K and 255.34 MPa. When THFA and DME were added as cosolvents the cloud-point for PTHFA + CO2 fluid shifted a lower pressure. The PC-SAFT model was applied to describe the phase behavior for all experimental results, which were adequately modeled. Through theoretical investigation with the PC-SAFT model, it was found that the strong interaction between polymer and CO2 causes wide one fluid for the PTHFA/CO2/THFA system, and the interactions between CO2 and DME molecules have strong effects on the phase behavior for the PTHFA/CO2/DME system." @default.
• W2790976720 created "2018-03-29" @default.
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• W2790976720 date "2018-05-01" @default.
• W2790976720 modified "2023-10-16" @default.
• W2790976720 title "Solubility on tetrahydrofurfuryl acrylate effect for the poly[tetrahydrofurfuryl acrylate] in supercritical carbon dioxide and dimethyl ether" @default.
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• W2790976720 doi "https://doi.org/10.1016/j.supflu.2018.01.026" @default.
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