FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2793014741> ?p ?o ?g. }

• W2793014741 endingPage "3490" @default.
• W2793014741 startingPage "3487" @default.
• W2793014741 abstract "Fine tuning nanoparticles with atomic precision is exciting and challenging and is critical for tuning the properties, understanding the structure-property correlation and determining the practical applications of nanoparticles. Some ultrasmall thiolated metal nanoparticles (metal nanoclusters) have been shown to be precisely doped, and even the protecting staple metal atom could be precisely reduced. However, the precise addition or reduction of the kernel atom while the other metal atoms in the nanocluster remain the same has not been successful until now, to the best of our knowledge. Here, by carefully selecting the protecting ligand with adequate steric hindrance, we synthesized a novel nanocluster in which the kernel can be regarded as that formed by the addition of two silver atoms to both ends of the Pt@Ag12 icosohedral kernel of the Ag24Pt(SR)18 (SR: thiolate) nanocluster, as revealed by single crystal X-ray crystallography. Interestingly, compared with the previously reported Ag24Pt(SR)18 nanocluster, the as-obtained novel bimetal nanocluster exhibits a similar absorption but a different electrochemical gap. One possible explanation for this result is that the kernel tuning does not essentially change the electronic structure, but obviously influences the charge on the Pt@Ag12 kernel, as demonstrated by natural population analysis, thus possibly resulting in the large electrochemical gap difference between the two nanoclusters. This work not only provides a novel strategy to tune metal nanoclusters but also reveals that the kernel change does not necessarily alter the optical and electrochemical gaps in a uniform manner, which has important implications for the structure-property correlation of nanoparticles." @default.
• W2793014741 created "2018-03-29" @default.
• W2793014741 creator A5009613920 @default.
• W2793014741 creator A5010168002 @default.
• W2793014741 creator A5015317024 @default.
• W2793014741 creator A5053856282 @default.
• W2793014741 creator A5058683121 @default.
• W2793014741 creator A5059515778 @default.
• W2793014741 creator A5066833385 @default.
• W2793014741 creator A5071069893 @default.
• W2793014741 creator A5088043650 @default.
• W2793014741 date "2018-02-22" @default.
• W2793014741 modified "2023-10-18" @default.
• W2793014741 title "Kernel Tuning and Nonuniform Influence on Optical and Electrochemical Gaps of Bimetal Nanoclusters" @default.
• W2793014741 cites W1806907900 @default.
• W2793014741 cites W1817448270 @default.
• W2793014741 cites W1963635535 @default.
• W2793014741 cites W1975320379 @default.
• W2793014741 cites W1978573177 @default.
• W2793014741 cites W1978634069 @default.
• W2793014741 cites W1980755415 @default.
• W2793014741 cites W1981334849 @default.
• W2793014741 cites W1988659705 @default.
• W2793014741 cites W1990886012 @default.
• W2793014741 cites W1993779520 @default.
• W2793014741 cites W2024167136 @default.
• W2793014741 cites W2024601105 @default.
• W2793014741 cites W2034183695 @default.
• W2793014741 cites W2037346419 @default.
• W2793014741 cites W2044701233 @default.
• W2793014741 cites W2054273170 @default.
• W2793014741 cites W2065084192 @default.
• W2793014741 cites W2066286007 @default.
• W2793014741 cites W2066778093 @default.
• W2793014741 cites W2068670668 @default.
• W2793014741 cites W2069807403 @default.
• W2793014741 cites W2069867993 @default.
• W2793014741 cites W2077228161 @default.
• W2793014741 cites W2078820160 @default.
• W2793014741 cites W2081185606 @default.
• W2793014741 cites W2090046309 @default.
• W2793014741 cites W2091273808 @default.
• W2793014741 cites W2091582826 @default.
• W2793014741 cites W2099992615 @default.
• W2793014741 cites W2105157003 @default.
• W2793014741 cites W2110311237 @default.
• W2793014741 cites W2131912981 @default.
• W2793014741 cites W2135097783 @default.
• W2793014741 cites W2140537016 @default.
• W2793014741 cites W2141686621 @default.
• W2793014741 cites W2154702768 @default.
• W2793014741 cites W2158051816 @default.
• W2793014741 cites W2244570801 @default.
• W2793014741 cites W2269323211 @default.
• W2793014741 cites W2312345857 @default.
• W2793014741 cites W2312658005 @default.
• W2793014741 cites W2326749880 @default.
• W2793014741 cites W2327998508 @default.
• W2793014741 cites W2329533941 @default.
• W2793014741 cites W2336168480 @default.
• W2793014741 cites W2336210380 @default.
• W2793014741 cites W2415860793 @default.
• W2793014741 cites W2460373497 @default.
• W2793014741 cites W2464661472 @default.
• W2793014741 cites W2470199101 @default.
• W2793014741 cites W2511591051 @default.
• W2793014741 cites W2514305421 @default.
• W2793014741 cites W2515286324 @default.
• W2793014741 cites W2539296124 @default.
• W2793014741 cites W2570380427 @default.
• W2793014741 cites W2590165672 @default.
• W2793014741 cites W2593916779 @default.
• W2793014741 cites W2614866349 @default.
• W2793014741 cites W2622344595 @default.
• W2793014741 cites W2623026738 @default.
• W2793014741 cites W2725869114 @default.
• W2793014741 cites W2763844153 @default.
• W2793014741 cites W4234750540 @default.
• W2793014741 cites W4246186748 @default.
• W2793014741 cites W4253300919 @default.
• W2793014741 doi "https://doi.org/10.1021/jacs.7b12083" @default.
• W2793014741 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29470909" @default.
• W2793014741 hasPublicationYear "2018" @default.
• W2793014741 type Work @default.
• W2793014741 sameAs 2793014741 @default.
• W2793014741 citedByCount "76" @default.
• W2793014741 countsByYear W27930147412018 @default.
• W2793014741 countsByYear W27930147412019 @default.
• W2793014741 countsByYear W27930147412020 @default.
• W2793014741 countsByYear W27930147412021 @default.
• W2793014741 countsByYear W27930147412022 @default.
• W2793014741 countsByYear W27930147412023 @default.
• W2793014741 crossrefType "journal-article" @default.
• W2793014741 hasAuthorship W2793014741A5009613920 @default.
• W2793014741 hasAuthorship W2793014741A5010168002 @default.
• W2793014741 hasAuthorship W2793014741A5015317024 @default.
• W2793014741 hasAuthorship W2793014741A5053856282 @default.
• W2793014741 hasAuthorship W2793014741A5058683121 @default.

• next