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- W2804497742 abstract "Scapolites are common volatile-bearing minerals in metamorphic rocks. In this study, the high-pressure behavior of an intermediate member of the scapolite solid solution series (Me47), chemical formula (Na1.86Ca1.86K0.23Fe0.01)(Al4.36Si7.64)O24[Cl0.48(CO3)0.48(SO4)0.01], has been investigated up to 17.79 GPa, by means of in situ single-crystal synchrotron X-ray diffraction. The isothermal elastic behavior of the studied scapolite has been described by a III-order Birch–Murnaghan equation of state, which provided the following refined parameters: V0 = 1110.6(7) Å3, $${K_{{V_0}}}$$ = 70(2) GPa ( $${beta _{{V_0}}}$$ = 0.0143(4) GPa−1) and $${K_{{V}}^prime}$$ = 4.8(7). The refined bulk modulus is intermediate between those previously reported for Me17 and Me68 scapolite samples, confirming that the bulk compressibility among the solid solution increases with the Na content. A discussion on the P-induced structure deformation mechanisms of tetragonal scapolite at the atomic scale is provided, along with the implications of the reported results for the modeling of scapolite stability. In addition, a single-crystal to single-crystal phase transition, which is displacive in character, has been observed toward a triclinic polymorph at 9.87 GPa. The high-pressure triclinic polymorph was found to be stable up to the highest pressure investigated." @default.
- W2804497742 created "2018-06-01" @default.
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- W2804497742 date "2018-05-21" @default.
- W2804497742 modified "2023-09-27" @default.
- W2804497742 title "High-pressure behavior of intermediate scapolite: compressibility, structure deformation and phase transition" @default.
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- W2804497742 doi "https://doi.org/10.1007/s00269-018-0976-8" @default.
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