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• W2805223670 startingPage "12708" @default.
• W2805223670 abstract "Abstract Boron(III) meso ‐lithiosubporphyrin was prepared by bromine–lithium exchange of B‐tolyl B III meso ‐bromosubporphyrin with n ‐butyllithium at −98 °C. The resulting subporphyrinyllithium was treated with various electrophiles such as benzophenone, N , N ‐dimethylformamide, CO 2 , chlorotrimethylsilane, N ‐fluorobenzenesulfonimide, and dimesitylboryl fluoride to give the corresponding meso ‐functionalized B III subporphyrins. The nucleophile was also used to construct B III subporphyrin dimers such as bis(B III subporphyrinyl)ketone, bis(B III subporphyrinyl)carbinol, and disilane‐bridged B III subporphyrin dimer. The structural, optical, and electrochemical properties of these meso ‐functionalized B III subporphyrins were examined by UV/Vis absorption and fluorescence spectroscopy, electrochemical studies, and DFT calculations." @default.
• W2805223670 created "2018-06-13" @default.
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• W2805223670 date "2018-07-19" @default.
• W2805223670 modified "2023-10-11" @default.
• W2805223670 title "<i>meso</i>‐Functionalization of Boron(III) Subporphyrin with Boron(III) <i>meso</i>‐Lithiosubporphyrin" @default.
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• W2805223670 doi "https://doi.org/10.1002/chem.201802339" @default.
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• W2805223670 hasPublicationYear "2018" @default.
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