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- W2836601706 abstract "To develop efficient compounds for photodynamic therapy (PDT) and boron neutron capture therapy (BNCT), many new types of derivatives of the tetrapyrrole macrocycle with polyhedral boron units within one molecule have been prepared over the past 20 years. The structure of the porphyrin macrocycle allows for the conjugation of several functionally different chemical moieties. These modifications can improve physical, chemical, and biological properties of the molecule, including amphiphilicity, bioavailability, metabolic stability, and antitumor potency. This chapter focuses on boronated analogs of synthetic porphyrins and chlorins with high boron content and boronated analogs of chlorin e6. It introduces a series of carboranylporphyrin congeners based on functional derivatives of 5,10,15,20-tetraphenylporphyrin and neutral and anionic derivatives of icosahedral carboranes. Fluorine nucleophilic substitution in the para-position of phenyl rings of 5,10,15,20-tetrakis (pentafluorophenyl) porphyrin and its metal complexes with neutral and anionic lithiocarboranes such as cesium 1-lithio-1-carba-closo dodecaborate, 1-lithio-o-carborane, and 1-lithio-2-phenyl-o-carborane resulted in fluorinated carboranylporphyrins." @default.
- W2836601706 created "2018-07-19" @default.
- W2836601706 creator A5051633061 @default.
- W2836601706 creator A5051907923 @default.
- W2836601706 creator A5068442652 @default.
- W2836601706 date "2018-04-24" @default.
- W2836601706 modified "2023-10-16" @default.
- W2836601706 title "Carborane Derivatives of Porphyrins and Chlorins for Photodynamic and Boron Neutron Capture Therapies" @default.
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- W2836601706 doi "https://doi.org/10.1002/9781119275602.ch3.3" @default.
- W2836601706 hasPublicationYear "2018" @default.
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