FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2887934981> ?p ?o ?g. }

• W2887934981 endingPage "219" @default.
• W2887934981 startingPage "210" @default.
• W2887934981 abstract "While fluoroquinolone (FQ) antibiotics are susceptible to degradation by sulfate and/or hydroxyl radicals formed in peroxymonosulfate (PMS) based advanced oxidation processes, here we report that unactivated PMS itself exhibits a specific high reactivity toward FQs for the first time. Reaction kinetics of PMS with two model FQs, ciprofloxacin (CF) and enrofloxacin (EF), showed a strong pH dependency with apparent second-order rate constants of 0.10-13.05 M-1s-1 for CF and 0.51-33.17 M-1s-1 for EF at pH 5-10. This pH dependency was well described by species-specific parallel reactions. On the basis of reaction kinetics and structure-activity assessment, the tertiary and secondary aliphatic N4 amines on the FQs' piperazine ring were proposed to be the main reaction sites. High performance liquid chromatography/electrospray ionization tandem mass analysis showed the formation of hydroxylated, N-oxide, and dealkylated products. Bacterial growth inhibition bioassays using Escherichia coli showed that oxidation products of FQs by PMS retained negligible antibacterial potency in comparison to parent FQs. Kinetic modeling using the rate constants estimated from pure water well predicted the oxidation kinetics of low levels of CF and EF by PMS in surface water. The degradation efficiency of FQs by PMS in surface water was slightly lower than that by ozone, comparable to that by ferrate, and much higher than that by permanganate. These results suggest that PMS is a promising oxidant for the treatment of FQs in water." @default.
• W2887934981 created "2018-08-22" @default.
• W2887934981 creator A5002352268 @default.
• W2887934981 creator A5002360271 @default.
• W2887934981 creator A5004375357 @default.
• W2887934981 creator A5027071448 @default.
• W2887934981 creator A5060175555 @default.
• W2887934981 creator A5065347809 @default.
• W2887934981 creator A5074237865 @default.
• W2887934981 creator A5077176563 @default.
• W2887934981 creator A5081252332 @default.
• W2887934981 date "2018-11-01" @default.
• W2887934981 modified "2023-10-17" @default.
• W2887934981 title "Oxidation of fluoroquinolone antibiotics by peroxymonosulfate without activation: Kinetics, products, and antibacterial deactivation" @default.
• W2887934981 cites W1966798508 @default.
• W2887934981 cites W1976119390 @default.
• W2887934981 cites W1976564748 @default.
• W2887934981 cites W1977592347 @default.
• W2887934981 cites W1983849784 @default.
• W2887934981 cites W1985025565 @default.
• W2887934981 cites W1987764100 @default.
• W2887934981 cites W2002122720 @default.
• W2887934981 cites W2006784241 @default.
• W2887934981 cites W2008294138 @default.
• W2887934981 cites W2009125083 @default.
• W2887934981 cites W2011727188 @default.
• W2887934981 cites W2017303728 @default.
• W2887934981 cites W2023830578 @default.
• W2887934981 cites W2037766564 @default.
• W2887934981 cites W2045015486 @default.
• W2887934981 cites W2050125681 @default.
• W2887934981 cites W2051347540 @default.
• W2887934981 cites W2053384919 @default.
• W2887934981 cites W2056386546 @default.
• W2887934981 cites W2059598963 @default.
• W2887934981 cites W2063509256 @default.
• W2887934981 cites W2069700993 @default.
• W2887934981 cites W2070609829 @default.
• W2887934981 cites W2072858339 @default.
• W2887934981 cites W2075039454 @default.
• W2887934981 cites W2077243803 @default.
• W2887934981 cites W2081709688 @default.
• W2887934981 cites W2108978957 @default.
• W2887934981 cites W2112740377 @default.
• W2887934981 cites W2118813171 @default.
• W2887934981 cites W2125420295 @default.
• W2887934981 cites W2148340648 @default.
• W2887934981 cites W2149496084 @default.
• W2887934981 cites W2205208012 @default.
• W2887934981 cites W2312635262 @default.
• W2887934981 cites W2319721068 @default.
• W2887934981 cites W2331816415 @default.
• W2887934981 cites W2347123726 @default.
• W2887934981 cites W2413402613 @default.
• W2887934981 cites W2469529613 @default.
• W2887934981 cites W2490108010 @default.
• W2887934981 cites W2593981259 @default.
• W2887934981 cites W2736350645 @default.
• W2887934981 cites W2736371272 @default.
• W2887934981 cites W2745875893 @default.
• W2887934981 cites W2753491988 @default.
• W2887934981 cites W2781745962 @default.
• W2887934981 cites W2792251660 @default.
• W2887934981 cites W2795041955 @default.
• W2887934981 cites W2799483626 @default.
• W2887934981 cites W2951387979 @default.
• W2887934981 cites W2951919496 @default.
• W2887934981 doi "https://doi.org/10.1016/j.watres.2018.08.026" @default.
• W2887934981 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30142519" @default.
• W2887934981 hasPublicationYear "2018" @default.
• W2887934981 type Work @default.
• W2887934981 sameAs 2887934981 @default.
• W2887934981 citedByCount "88" @default.
• W2887934981 countsByYear W28879349812019 @default.
• W2887934981 countsByYear W28879349812020 @default.
• W2887934981 countsByYear W28879349812021 @default.
• W2887934981 countsByYear W28879349812022 @default.
• W2887934981 countsByYear W28879349812023 @default.
• W2887934981 crossrefType "journal-article" @default.
• W2887934981 hasAuthorship W2887934981A5002352268 @default.
• W2887934981 hasAuthorship W2887934981A5002360271 @default.
• W2887934981 hasAuthorship W2887934981A5004375357 @default.
• W2887934981 hasAuthorship W2887934981A5027071448 @default.
• W2887934981 hasAuthorship W2887934981A5060175555 @default.
• W2887934981 hasAuthorship W2887934981A5065347809 @default.
• W2887934981 hasAuthorship W2887934981A5074237865 @default.
• W2887934981 hasAuthorship W2887934981A5077176563 @default.
• W2887934981 hasAuthorship W2887934981A5081252332 @default.
• W2887934981 hasConcept C121332964 @default.
• W2887934981 hasConcept C139066938 @default.
• W2887934981 hasConcept C13965031 @default.
• W2887934981 hasConcept C148898269 @default.
• W2887934981 hasConcept C162356407 @default.
• W2887934981 hasConcept C178790620 @default.
• W2887934981 hasConcept C185592680 @default.
• W2887934981 hasConcept C2776201271 @default.
• W2887934981 hasConcept C2776778087 @default.
• W2887934981 hasConcept C36663273 @default.

• next