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- W2905690114 abstract "A Zn(II) complex with coumarin-hydrazone ligand, [ZnCl(HL)(CH3OH)0.76(H2O)0.24]·0.24(CH3OH) (1), was synthesized from the reaction of equimolar amount of ZnCl2·4H2O and (E)-2-hydroxy-N′-(1-(2-oxo-2H-chromen-3-yl)ethylidene)benzohydrazide (H2L) in methanol solvent. The complex was characterized by elemental analysis, spectroscopic methods and single crystal X-ray diffraction studies. Single crystal X-ray analysis indicated that the Zn(II) ion in complex 1 has a distorted square pyramidal environment and the coumarin-hydrazone ligand is coordinated as a mononegative tridentate ONO-donor ligand, (HL)−. The photoluminescent studies indicated that complex 1 has emission at about 470 nm. The catalytic potential of complex 1 was investigated for preparing tetrazole based compounds from the azide-nitrile cycloaddition reactions. The catalytic reactions were carried out in water as a green solvent. The results indicated that complex 1 is an active catalyst for preparing tetrazole compounds. The effects of temperature and electronic properties of the substituent connected to the nitrile group on the activity of this catalytic system were also considered." @default.
- W2905690114 created "2019-01-01" @default.
- W2905690114 creator A5022827414 @default.
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- W2905690114 creator A5045065300 @default.
- W2905690114 creator A5045685537 @default.
- W2905690114 creator A5061073220 @default.
- W2905690114 date "2019-03-01" @default.
- W2905690114 modified "2023-09-25" @default.
- W2905690114 title "Synthesis, crystal structure and investigation of the catalytic and spectroscopic properties of a Zn(II) complex with coumarin-hydrazone ligand" @default.
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- W2905690114 doi "https://doi.org/10.1016/j.poly.2018.12.023" @default.
- W2905690114 hasPublicationYear "2019" @default.
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