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• W2912309937 endingPage "3520" @default.
• W2912309937 startingPage "3515" @default.
• W2912309937 abstract "Freestanding nanopapers were fabricated by the assembly of metal-organic frameworks (MOFs) onto cellulose nanofibers (CNFs). The CNFs are wrapped by continuously nucleated MOF layers (CNF@MOF) by interfacial synthesis, with the charge density on the surface of the CNFs and the dosage of the surfactant polyvinylpyrrolidone (PVP) being carefully adjusted. The obtained CNF@MOF nanofibers with long-range, continuous, hybrid nanostructures were very different to the composites formed by aggregation of MOF nanoparticles on the substrates. Four typical MOFs (HKUST-1, Al-MIL-53, Zn-MOF-74, ZIF-CO3 -1) were successfully grown onto CNFs in aqueous solutions and further fabricated into freestanding nanopapers. Because of their unique nanostructures and morphologies, the corresponding flexible nanopapers exhibit hierarchical meso-micropores, high optical transparency, high thermal stability, and high mechanical strength. A proof-of-concept study shows that the CNF@MOF nanopapers can be used as efficient filters to separate volatile organic compounds (VOCs) from the air. This work provides a new path for structuring MOF materials that may boost their practical application." @default.
• W2912309937 created "2019-02-21" @default.
• W2912309937 creator A5015628505 @default.
• W2912309937 creator A5027412973 @default.
• W2912309937 creator A5037359873 @default.
• W2912309937 date "2019-02-12" @default.
• W2912309937 modified "2023-10-18" @default.
• W2912309937 title "Highly Transparent, Flexible, and Mechanically Strong Nanopapers of Cellulose Nanofibers @Metal–Organic Frameworks" @default.
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• W2912309937 doi "https://doi.org/10.1002/chem.201806417" @default.
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• W2912309937 hasPublicationYear "2019" @default.
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