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• W2912320512 abstract "The construction of all-solid-state batteries is now easier after the successful synthesis of sulfur-based solid electrolytes with extremely high ionic conductivities. Utilizing lithium metal as the anode in these batteries requires a protective solid electrolyte layer to prevent corrosion due to the highly reactive nature of lithium. Li3N coating on lithium metal is a promising way of preventing the degradation of the electrolyte during charge and discharge. In this study, utilization of a Li3N-coated lithium anode and Li7P3S11 solid electrolyte are reported, where a quaternary reduced graphene oxide (rGO)/S/carbon black/Li7P3S11 composite is used as cathode in the assembled cell. Our results indicate that protecting the Li metal with a Li3N coating does not affect the electrochemical characteristics of the cell and extends the cycle life of the battery. A cell assembled with a protective layer was shown to having 306 mAh g−1 capacity after 120 cycles at 160 mAh g−1 current density, whereas a cell without protective layer had a capacity of 260 mAh g−1." @default.
• W2912320512 created "2019-02-21" @default.
• W2912320512 creator A5048797077 @default.
• W2912320512 creator A5068202228 @default.
• W2912320512 date "2019-02-01" @default.
• W2912320512 modified "2023-09-26" @default.
• W2912320512 title "Assembling All-Solid-State Lithium-Sulfur Batteries with Li₃ N-Protected Anodes" @default.
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• W2912320512 doi "https://doi.org/10.1002/cplu.201800539" @default.
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