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- W2949082682 abstract "The scope of the NCS-mediated amination/[2,3]-sigmatropic rearrangement of enantioenriched allylic selenides has been expanded to provide access to three new product classes. The use of N-protected amino acid amides provides a novel strategy for accessing peptide chains containing unnatural vinyl glycine amino acid residues. Also reported is the use of amino acid esters, allowing the diastereoselective synthesis of N,N-dicarboxymethylamines, a motif found in a number of pharmaceuticals. Furthermore, use of a range of N-aromatic and N-heteroaromatic amines allows the formation of enantioenriched N-arylamino acids, a motif found in a number of synthetically and biologically interesting compounds." @default.
- W2949082682 created "2019-06-27" @default.
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- W2949082682 date "2014-04-10" @default.
- W2949082682 modified "2023-10-03" @default.
- W2949082682 title "[2,3]-Sigmatropic Rearrangement of Allylic Selenimides: Strategy for the Synthesis of Peptides, Peptidomimetics, and <i>N</i>-Aryl Vinyl Glycines" @default.
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- W2949082682 doi "https://doi.org/10.1021/jo500341e" @default.
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