FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2964693012> ?p ?o ?g. }

• W2964693012 endingPage "10693" @default.
• W2964693012 startingPage "10686" @default.
• W2964693012 abstract "We have demonstrated the effect of a solvent at the second coordination sphere on slow relaxation of magnetization for hepta-coordinated cobalt(II) complexes with the formulas [Co(H4L)(DMF)(H2O)](NO3)2·(DMF) (1), [Co(H4L)(MeOH)(H2O)](NO3)2·(MeOH) (2), and [Co(H4L)(DEF)(H2O)](NO3)2 (3) (H4L = 2,2′-(pyridine-2,6-diylbis(ethan-1-yl-1-ylidene))bis(N-phenylhydrazinecarboxamide). Structural analysis reveals that the presence of lattice solvent molecule in 1 and 2 dramatically changes the crystal packing and noncovalent interactions as compared to 3 where no solvent molecule is present in the crystal lattice. The dc and ac magnetic susceptibility measurements reveal the presence of easy-plane magnetic anisotropy for all the complexes, and field induced slow relaxation behavior has been observed above 2 K for 1 and 2 in contrast to 3 due to the availability of the solvent molecules in the crystal lattice. The ab initio calculations further support the sign of D and the negligible effect of the first co-ordination sphere, as almost similar D values were obtained for all the complexes. The field and temperature dependence of relaxation time confirm that quantum tunnelling of magnetization (QTM) plays a major role in slow magnetic relaxation, and thermal dependence like an optical or acoustic Raman pathway is also important. To further analyze the effect of dipole–dipole interaction on slow magnetic relaxation, a dilution experiment has been performed." @default.
• W2964693012 created "2019-08-13" @default.
• W2964693012 creator A5030031955 @default.
• W2964693012 creator A5040324814 @default.
• W2964693012 creator A5061111338 @default.
• W2964693012 date "2019-08-05" @default.
• W2964693012 modified "2023-10-05" @default.
• W2964693012 title "Sizeable Effect of Lattice Solvent on Field Induced Slow Magnetic Relaxation in Seven Coordinated Co^II Complexes" @default.
• W2964693012 cites W1720276026 @default.
• W2964693012 cites W1819117861 @default.
• W2964693012 cites W1834882820 @default.
• W2964693012 cites W1943237854 @default.
• W2964693012 cites W1969360633 @default.
• W2964693012 cites W1970881901 @default.
• W2964693012 cites W1974222665 @default.
• W2964693012 cites W1979303409 @default.
• W2964693012 cites W1981783914 @default.
• W2964693012 cites W1985741378 @default.
• W2964693012 cites W1990654323 @default.
• W2964693012 cites W1992996545 @default.
• W2964693012 cites W1997041494 @default.
• W2964693012 cites W2006732735 @default.
• W2964693012 cites W2011933569 @default.
• W2964693012 cites W2018227294 @default.
• W2964693012 cites W2023071471 @default.
• W2964693012 cites W2025031859 @default.
• W2964693012 cites W2026039351 @default.
• W2964693012 cites W2043349685 @default.
• W2964693012 cites W2043601493 @default.
• W2964693012 cites W2052312990 @default.
• W2964693012 cites W2057902656 @default.
• W2964693012 cites W2059205366 @default.
• W2964693012 cites W2063626543 @default.
• W2964693012 cites W2065025351 @default.
• W2964693012 cites W2067718414 @default.
• W2964693012 cites W2080665513 @default.
• W2964693012 cites W2082501995 @default.
• W2964693012 cites W2084239075 @default.
• W2964693012 cites W2089740902 @default.
• W2964693012 cites W2091901086 @default.
• W2964693012 cites W2100113961 @default.
• W2964693012 cites W2106989305 @default.
• W2964693012 cites W2117867509 @default.
• W2964693012 cites W2119498495 @default.
• W2964693012 cites W2122037965 @default.
• W2964693012 cites W2152267943 @default.
• W2964693012 cites W2152765125 @default.
• W2964693012 cites W2158019178 @default.
• W2964693012 cites W2180053483 @default.
• W2964693012 cites W2211195160 @default.
• W2964693012 cites W2278356249 @default.
• W2964693012 cites W2315614157 @default.
• W2964693012 cites W2319933727 @default.
• W2964693012 cites W2321264486 @default.
• W2964693012 cites W2321893305 @default.
• W2964693012 cites W2324747253 @default.
• W2964693012 cites W2327045856 @default.
• W2964693012 cites W2327264987 @default.
• W2964693012 cites W2329653445 @default.
• W2964693012 cites W2332200090 @default.
• W2964693012 cites W2333630521 @default.
• W2964693012 cites W2339245912 @default.
• W2964693012 cites W2345560148 @default.
• W2964693012 cites W2412991928 @default.
• W2964693012 cites W2439570865 @default.
• W2964693012 cites W2472971450 @default.
• W2964693012 cites W2522946598 @default.
• W2964693012 cites W2528136433 @default.
• W2964693012 cites W2549302171 @default.
• W2964693012 cites W2566335857 @default.
• W2964693012 cites W2596398895 @default.
• W2964693012 cites W2602969401 @default.
• W2964693012 cites W2606073954 @default.
• W2964693012 cites W2607249591 @default.
• W2964693012 cites W2618143612 @default.
• W2964693012 cites W2618436321 @default.
• W2964693012 cites W2626631587 @default.
• W2964693012 cites W2747139713 @default.
• W2964693012 cites W2749576414 @default.
• W2964693012 cites W2769441175 @default.
• W2964693012 cites W2785687508 @default.
• W2964693012 cites W2802889601 @default.
• W2964693012 cites W2806931125 @default.
• W2964693012 cites W2887611681 @default.
• W2964693012 cites W2894557875 @default.
• W2964693012 cites W2896968078 @default.
• W2964693012 cites W2897628202 @default.
• W2964693012 cites W2898785881 @default.
• W2964693012 cites W2900308813 @default.
• W2964693012 cites W2901080522 @default.
• W2964693012 cites W4237560963 @default.
• W2964693012 doi "https://doi.org/10.1021/acs.inorgchem.9b00615" @default.
• W2964693012 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31379159" @default.
• W2964693012 hasPublicationYear "2019" @default.
• W2964693012 type Work @default.
• W2964693012 sameAs 2964693012 @default.
• W2964693012 citedByCount "31" @default.
• W2964693012 countsByYear W29646930122019 @default.

• next