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• W2983513612 abstract "Piezoelectricity as a bulk phenomenon in crystals is well understood from scientific, mathematical and engineering perspectives and has found wide use in many devices that convert electrical to mechanical energy or vice versa. Many strong piezoelectric compounds are inorganic, stiff ceramics that possess large piezoelectric coefficients but may have non-ideal properties for some applications e.g. related to cost, toxicity, biocompatibility, and incidenceof fracture over time. Currently work is being done to create flexible and soft piezoelectric materials from organic compounds to make new, smart materials that could be used in medical, industrial, robotic and other technological applications. To this end the ability toscreen for good organic piezoelectrics is necessary and requires a fundamental understanding of piezoelectricity at the molecular and nanoscale level. At the heart of macroscopic piezoelectric properties are inter- and intramolecular interactions and the different deformationresponse properties of these interactions in an applied electric field. This thesis investigates the linear response properties of molecules and small (aperiodic) systems the building blocks for macroscopic and nano-scale piezoelectric materials and develops methods and formalismswith roots in strain theory to help better understand which types of inter- and intramolecular interactions are best suited to yield piezoelectric systems with specifically tailored responses to applied electric fields. At the same time, the methods and formalism presented here havepotential applications in the control of nanomachines via electric fields." @default.
• W2983513612 created "2019-11-22" @default.
• W2983513612 creator A5040309562 @default.
• W2983513612 date "2019-09-25" @default.
• W2983513612 modified "2023-09-27" @default.
• W2983513612 title "Mechanical deformation of aperiodic organic systems in response to electrostatic fields: molecular piezoelectricity" @default.
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