Matches in SemOpenAlex for { <https://semopenalex.org/work/W298935559> ?p ?o ?g. }
- W298935559 endingPage "70" @default.
- W298935559 startingPage "33" @default.
- W298935559 abstract "Abstract Adsorption of inorganic and organic solutes by clay minerals, including competitive or synergetic effects in multisolute systems, has direct impacts on the rates and mechanisms of chemical transfer through clay barriers. Adsorption of ions, molecules and low- and high-molecular mass compounds may influence (1) clay mineral hydration and swelling, (2) mineral porosity and surface coating, (3) the development of bioorganic phases associated with clay minerals, and (4) surface tension at the clay mineral–water interface. The goal of this chapter is to summarize the major mechanisms controlling clay mineral interactions with inorganic and organic species (cations, anions, and molecules) and to discuss their relationships with the surfaces and interfaces of clay minerals. Regarding inorganic solutes, the chapter discusses cation exchange, surface complexation, and metal substitution reactions in the clay mineral structure, emphasizing the role of the interlayer space and edges, outer- and innersphere complex formation, and the contributions of electrostatic and covalent interactions to inorganic solute adsorption by clay minerals. The role of solute–bulk water interactions and the various effects of surface-associated water on adsorption of organic solutes by clay minerals are discussed, with an emphasis on the possible use of linear free energy relationships for the analysis of adsorption interactions. The interactions of clay mineral surfaces in soils and sediments with natural organic matter (NOM) and natural nanoparticles of other minerals are briefly reviewed, as these are relevant for engineered and environmental applications of clay minerals. In addition, the interactions of metal and metalloid ions and organic compounds with clay minerals in natural and engineered environments, the interfering effects of NOM, metal oxides, dissolved organic matter, and the impact of wetting–drying processes on the ability of clay minerals to interact with solutes are reviewed. Finally, some gaps in the current knowledge and critical research priorities are identified." @default.
- W298935559 created "2016-06-24" @default.
- W298935559 creator A5009517172 @default.
- W298935559 creator A5087697033 @default.
- W298935559 date "2015-01-01" @default.
- W298935559 modified "2023-10-16" @default.
- W298935559 title "Adsorption of Inorganic and Organic Solutes by Clay Minerals" @default.
- W298935559 cites W1964106797 @default.
- W298935559 cites W1964761867 @default.
- W298935559 cites W1965320774 @default.
- W298935559 cites W1966173010 @default.
- W298935559 cites W1968551688 @default.
- W298935559 cites W1969235078 @default.
- W298935559 cites W1970917007 @default.
- W298935559 cites W1971615835 @default.
- W298935559 cites W1972739479 @default.
- W298935559 cites W1981026196 @default.
- W298935559 cites W1983163750 @default.
- W298935559 cites W1985812655 @default.
- W298935559 cites W1987626082 @default.
- W298935559 cites W1987757992 @default.
- W298935559 cites W1989381884 @default.
- W298935559 cites W1989596055 @default.
- W298935559 cites W1990171813 @default.
- W298935559 cites W1992606584 @default.
- W298935559 cites W1992681627 @default.
- W298935559 cites W1993512184 @default.
- W298935559 cites W1993742331 @default.
- W298935559 cites W1995106393 @default.
- W298935559 cites W1995893501 @default.
- W298935559 cites W1996629922 @default.
- W298935559 cites W1997195748 @default.
- W298935559 cites W1997812034 @default.
- W298935559 cites W1997854365 @default.
- W298935559 cites W1998233272 @default.
- W298935559 cites W2002771354 @default.
- W298935559 cites W2004537338 @default.
- W298935559 cites W2005155820 @default.
- W298935559 cites W2005820136 @default.
- W298935559 cites W2008663824 @default.
- W298935559 cites W2009229614 @default.
- W298935559 cites W2012533648 @default.
- W298935559 cites W2013741856 @default.
- W298935559 cites W2014938854 @default.
- W298935559 cites W2015517515 @default.
- W298935559 cites W2021162607 @default.
- W298935559 cites W2022143098 @default.
- W298935559 cites W2022789754 @default.
- W298935559 cites W2025150226 @default.
- W298935559 cites W2025997425 @default.
- W298935559 cites W2029063865 @default.
- W298935559 cites W2035496257 @default.
- W298935559 cites W2039762763 @default.
- W298935559 cites W2044565154 @default.
- W298935559 cites W2045462089 @default.
- W298935559 cites W2046761316 @default.
- W298935559 cites W2048955725 @default.
- W298935559 cites W2050900513 @default.
- W298935559 cites W2051195074 @default.
- W298935559 cites W2051660397 @default.
- W298935559 cites W2055429889 @default.
- W298935559 cites W2058019597 @default.
- W298935559 cites W2058435830 @default.
- W298935559 cites W2065318749 @default.
- W298935559 cites W2067552268 @default.
- W298935559 cites W2070921978 @default.
- W298935559 cites W2071704940 @default.
- W298935559 cites W2074395278 @default.
- W298935559 cites W2074888395 @default.
- W298935559 cites W2075394418 @default.
- W298935559 cites W2079844202 @default.
- W298935559 cites W2082946832 @default.
- W298935559 cites W2083322852 @default.
- W298935559 cites W2083324464 @default.
- W298935559 cites W2086487597 @default.
- W298935559 cites W2087430270 @default.
- W298935559 cites W2087695930 @default.
- W298935559 cites W2092414735 @default.
- W298935559 cites W2094347759 @default.
- W298935559 cites W2107838687 @default.
- W298935559 cites W2111180170 @default.
- W298935559 cites W2111289042 @default.
- W298935559 cites W2112372171 @default.
- W298935559 cites W2119492070 @default.
- W298935559 cites W2122250081 @default.
- W298935559 cites W2125893523 @default.
- W298935559 cites W2127395101 @default.
- W298935559 cites W2131838410 @default.
- W298935559 cites W2138438084 @default.
- W298935559 cites W2138743792 @default.
- W298935559 cites W2141455307 @default.
- W298935559 cites W2154310852 @default.
- W298935559 cites W2156541269 @default.
- W298935559 cites W2156581665 @default.
- W298935559 cites W2161129521 @default.
- W298935559 cites W2227147571 @default.
- W298935559 cites W2313886528 @default.
- W298935559 cites W2314653047 @default.