FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2999371129> ?p ?o ?g. }

• W2999371129 endingPage "273" @default.
• W2999371129 startingPage "273" @default.
• W2999371129 abstract "Synthesis of new chromium(II) complexes with chelating bis(alkoxide) ligand [OO]Ph (H2[OO]Ph = [1,1′:4′,1′’-terphenyl]-2,2′’-diylbis(diphenylmethanol)) and their subsequent reactivity in the context of catalytic production of carbodiimides from azides and isocyanides are described. Two different Cr(II) complexes are obtained, as a function of the crystallization solvent: mononuclear Cr[OO]Ph(THF)2 (in toluene/THF, THF = tetrahydrofuran) and dinuclear Cr2([OO]Ph)2 (in CH2Cl2/THF). The electronic structure and bonding in Cr[OO]Ph(THF)2 were probed by density functional theory calculations. Isolated Cr2([OO]Ph)2 undergoes facile reaction with 4-MeC6H4N3, 4-MeOC6H4N3, or 3,5-Me2C6H3N3 to yield diamagnetic Cr(VI) bis(imido) complexes; a structure of Cr[OO]Ph(N(4-MeC6H4))2 was confirmed by X-ray crystallography. The reaction of Cr2([OO]Ph)2 with bulkier azides N3R (MesN3, AdN3) forms paramagnetic products, formulated as Cr[OO]Ph(NR). The attempted formation of a Cr–alkylidene complex (using N2CPh2) instead forms chromium(VI) bis(diphenylmethylenehydrazido) complex Cr[OO]Ph(NNCPh2)2. Catalytic formation of carbodiimides was investigated for the azide/isocyanide mixtures containing various aryl azides and isocyanides. The formation of carbodiimides was found to depend on the nature of organoazide: whereas bulky mesitylazide led to the formation of carbodiimides with all isocyanides, no carbodiimide formation was observed for 3,5-dimethylphenylazide or 4-methylphenylazide. Treatment of Cr2([OO]Ph)2 or H2[OO]Ph with NO+ leads to the formation of [1,2-b]-dihydroindenofluorene, likely obtained via carbocation-mediated cyclization of the ligand." @default.
• W2999371129 created "2020-01-23" @default.
• W2999371129 creator A5016565779 @default.
• W2999371129 creator A5020283859 @default.
• W2999371129 creator A5035971821 @default.
• W2999371129 creator A5076502565 @default.
• W2999371129 date "2020-01-09" @default.
• W2999371129 modified "2023-09-27" @default.
• W2999371129 title "Synthesis of Chromium(II) Complexes with Chelating Bis(alkoxide) Ligand and Their Reactions with Organoazides and Diazoalkanes" @default.
• W2999371129 cites W1899165060 @default.
• W2999371129 cites W1915458723 @default.
• W2999371129 cites W1976801308 @default.
• W2999371129 cites W1988091937 @default.
• W2999371129 cites W1997740585 @default.
• W2999371129 cites W2009965873 @default.
• W2999371129 cites W2023514287 @default.
• W2999371129 cites W2030687437 @default.
• W2999371129 cites W2040829971 @default.
• W2999371129 cites W2075689717 @default.
• W2999371129 cites W2078598492 @default.
• W2999371129 cites W2086186090 @default.
• W2999371129 cites W2086957099 @default.
• W2999371129 cites W2092157292 @default.
• W2999371129 cites W2094844841 @default.
• W2999371129 cites W2096747776 @default.
• W2999371129 cites W2120681666 @default.
• W2999371129 cites W2132525235 @default.
• W2999371129 cites W2133497030 @default.
• W2999371129 cites W2170228822 @default.
• W2999371129 cites W2224728609 @default.
• W2999371129 cites W2235326471 @default.
• W2999371129 cites W2289638120 @default.
• W2999371129 cites W2319591706 @default.
• W2999371129 cites W2331592989 @default.
• W2999371129 cites W2408830764 @default.
• W2999371129 cites W2443960070 @default.
• W2999371129 cites W2468288616 @default.
• W2999371129 cites W2507318159 @default.
• W2999371129 cites W2601407920 @default.
• W2999371129 cites W2613044615 @default.
• W2999371129 cites W2726731743 @default.
• W2999371129 cites W2742295368 @default.
• W2999371129 cites W2745179143 @default.
• W2999371129 cites W2763945171 @default.
• W2999371129 cites W2767826955 @default.
• W2999371129 cites W2781519417 @default.
• W2999371129 cites W2791867329 @default.
• W2999371129 cites W2802657910 @default.
• W2999371129 cites W2804571367 @default.
• W2999371129 cites W2805608201 @default.
• W2999371129 cites W2884681372 @default.
• W2999371129 cites W2897580722 @default.
• W2999371129 cites W2912376221 @default.
• W2999371129 cites W2914448459 @default.
• W2999371129 cites W2944912390 @default.
• W2999371129 cites W2950891723 @default.
• W2999371129 cites W2953470930 @default.
• W2999371129 cites W2959005278 @default.
• W2999371129 cites W2966765640 @default.
• W2999371129 cites W2967658974 @default.
• W2999371129 cites W2972644554 @default.
• W2999371129 cites W2976671248 @default.
• W2999371129 cites W2991603991 @default.
• W2999371129 cites W2992392235 @default.
• W2999371129 cites W407807437 @default.
• W2999371129 cites W4250342449 @default.
• W2999371129 doi "https://doi.org/10.3390/molecules25020273" @default.
• W2999371129 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7024303" @default.
• W2999371129 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31936557" @default.
• W2999371129 hasPublicationYear "2020" @default.
• W2999371129 type Work @default.
• W2999371129 sameAs 2999371129 @default.
• W2999371129 citedByCount "6" @default.
• W2999371129 countsByYear W29993711292021 @default.
• W2999371129 countsByYear W29993711292022 @default.
• W2999371129 crossrefType "journal-article" @default.
• W2999371129 hasAuthorship W2999371129A5016565779 @default.
• W2999371129 hasAuthorship W2999371129A5020283859 @default.
• W2999371129 hasAuthorship W2999371129A5035971821 @default.
• W2999371129 hasAuthorship W2999371129A5076502565 @default.
• W2999371129 hasBestOaLocation W29993711291 @default.
• W2999371129 hasConcept C116569031 @default.
• W2999371129 hasConcept C142724271 @default.
• W2999371129 hasConcept C155647269 @default.
• W2999371129 hasConcept C161790260 @default.
• W2999371129 hasConcept C170493617 @default.
• W2999371129 hasConcept C178790620 @default.
• W2999371129 hasConcept C179104552 @default.
• W2999371129 hasConcept C185592680 @default.
• W2999371129 hasConcept C188027245 @default.
• W2999371129 hasConcept C204787440 @default.
• W2999371129 hasConcept C2776701986 @default.
• W2999371129 hasConcept C2776910235 @default.
• W2999371129 hasConcept C2777010268 @default.
• W2999371129 hasConcept C2778839380 @default.
• W2999371129 hasConcept C2780263894 @default.
• W2999371129 hasConcept C2780471494 @default.
• W2999371129 hasConcept C2781076698 @default.

• next