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- W2999682779 abstract "With the rapid development of spacecraft such as rocket, it is increasingly important to develop high-energy and sustainable fuels. Biofuels synthesized from biomass derivatives provide great convenience for sustainable development. In this work, we reported a route for synthesis of high-energy cyclopropane bio-kerosene by cyclopropanation of myrcene with zinc carbenoid. The reaction conditions including reaction time, reaction temperature, solvent and molar ratio were optimized. Finally, a tricyclic cyclopropane bio-kerosene was synthesized with 69.8% yield under optimum conditions (i.e. zinc carbenoid synthesis temperature of −15 °C, cyclopropanation temperature of 25 °C and solvent of dichloromethane). Importantly, this bio-kerosene possesses a high specific impulse of 328.25 s, much better than the commercial rocket kerosene RP-1, as well as a high net-heat-value of 43.4 MJ/kg and good low-temperature properties." @default.
- W2999682779 created "2020-01-23" @default.
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- W2999682779 date "2020-05-01" @default.
- W2999682779 modified "2023-10-10" @default.
- W2999682779 title "Synthesis of strained high-energy rocket bio-kerosene via cyclopropanation of myrcene" @default.
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- W2999682779 doi "https://doi.org/10.1016/j.fuproc.2020.106339" @default.
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