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- W3007201520 abstract "Here, surfactant free composite catalysts (Pd–Cu/rGO) with Pd–Cu alloy nanoparticles uniformly distributed on graphene sheets are successfully prepared via a facile hydrothermal approach. Compared with pure Pd/rGO catalyst, the introduction of copper could dramatically enhance the performance of the catalyst in the electrocatalytic formic acid oxidation (FAO) due to the strain effect and the ligand effect. With the optimized atomic ratio of 3:1 between palladium and copper, the alloy nanoparticle shows the smallest size of 2.12 nm, thus endowing the composite catalyst with highest catalytic efficiency. With Pd load as low as 14.5%, a maximum mass current density of 1580 mA mgPd−1, and residual current of 69.93 mA mgPd−1 at 3000 s was achieved with our Pd3Cu1/rGO catalyst in the electrocatalytic FAO process." @default.
- W3007201520 created "2020-03-06" @default.
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- W3007201520 date "2020-04-01" @default.
- W3007201520 modified "2023-10-17" @default.
- W3007201520 title "Synthesis of ultrafine low loading Pd–Cu alloy catalysts supported on graphene with excellent electrocatalytic performance for formic acid oxidation" @default.
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- W3007201520 doi "https://doi.org/10.1016/j.ijhydene.2020.02.019" @default.
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