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- W3023372989 endingPage "228134" @default.
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- W3023372989 abstract "This study investigates the novel use of propionitrile (PN) as the single organic solvent for high-voltage carbon/carbon capacitors. Quaternary ammonium salts spiro-(1,1ʹ)-bipyrrolidinium tetrafluoroborate (SBPBF4) and 1,1-dimethylpyrrolidinium tetrafluoroborate (DMPBF4) dissolved in acetonitrile (AN) and propionitrile (PN) are compared. PN-based electrolytes exhibit a large and symmetric electrochemical stability, an exceptional anodic potential limit, good ionic conductivity, and low viscosity, allowing EDLCs to operate at 3.5 V even with a high current density (2.5 A g−1). Moreover, PN-based electrolytes can suppress the anodic dissolution of the Al current collector at a high potential. These advantages help in the realization of EDLCs with excellent cycling stabilities at high voltages. As a result, at 3.5 V, EDLCs with PN-based electrolytes exhibit the highest energy and power density of 49.3 Wh kg−1 and 22.9 kW kg−1, respectively. Therefore, the electrolyte systems reported here could be a promising electrolyte candidate to replace currently commercialized electrolytes for practical applications." @default.
- W3023372989 created "2020-05-13" @default.
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- W3023372989 date "2020-07-01" @default.
- W3023372989 modified "2023-10-16" @default.
- W3023372989 title "Propionitrile as a single organic solvent for high voltage electric double-layer capacitors" @default.
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- W3023372989 doi "https://doi.org/10.1016/j.jpowsour.2020.228134" @default.
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