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• W3047804530 endingPage "12121" @default.
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• W3047804530 abstract "The potential of the perovskite system Nd1–xSrxCoO3−δ (x = 1/3 and 2/3) as cathode material for solid oxide fuel cells (SOFCs) has been investigated via detailed structural, electrical, and electrochemical characterization. The average structure of x = 1/3 is orthorhombic with a complex microstructure consisting of intergrown, adjacent, perpendicularly oriented domains. This orthorhombic symmetry remains throughout the temperature range 373–1073 K, as observed by neutron powder diffraction. A higher Sr content of x = 2/3 leads to stabilization of the cubic perovskite with a homogeneous microstructure and with a higher oxygen vacancy content and cobalt oxidation state than the orthorhombic phase at SOFC operation temperature. Both materials are p-type electronic conductors with high total conductivities of 690 and 1675 S·cm–1 at 473 K in air for x = 1/3 and 2/3, respectively. Under working conditions, both compounds exhibit similar electronic conductivities, since x = 2/3 loses more oxygen on heating than x = 1/3, associated with a greater loss of p-type charger carriers. However, composite cathodes prepared with Nd1/3Sr2/3CoO3−δ and Ce0.8Gd0.2O2−δ present lower ASR values (0.10 Ω·cm2 at 973 K in air) than composites prepared with Nd2/3Sr1/3CoO3−δ and Ce0.8Gd0.2O2−δ (0.34 Ω·cm2). The high activity for the oxygen electrochemical reaction at intermediate temperatures is likely attributable to a large disordered oxygen-vacancy concentration, resulting in a very promising SOFC cathode for real devices." @default.
• W3047804530 created "2020-08-13" @default.
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• W3047804530 date "2020-08-07" @default.
• W3047804530 modified "2023-09-30" @default.
• W3047804530 title "The Effects of Sr Content on the Performance of Nd_1–<i>x</i>Sr_<i>x</i>CoO_3−δ Air-Electrode Materials for Intermediate Temperature Solid Oxide Fuel Cells under Operational Conditions" @default.
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• W3047804530 doi "https://doi.org/10.1021/acs.inorgchem.0c01049" @default.
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• W3047804530 hasPublicationYear "2020" @default.
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