FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3050368757> ?p ?o ?g. }

• W3050368757 endingPage "21064" @default.
• W3050368757 startingPage "21058" @default.
• W3050368757 abstract "Significance Copper-catalyzed carbon–nitrogen bond formation has the potential to provide efficient synthetic access to medicinally relevant organic molecules, but broad use of the coupling has been hampered by the requirement for an energetically challenging substrate activation step (oxidative addition into an aryl halide). Here we report a mechanistic alternative that circumvents oxidative addition by cooperatively employing photochemically generated silicon-centered radicals and copper to activate aryl halides via a one-electron pathway. This dramatically increases the range of accessible products, thereby allowing room-temperature synthesis of a diverse electronic and steric range of products traditionally considered inaccessible via copper catalysis due to the prohibitively high barrier for direct copper oxidative addition." @default.
• W3050368757 created "2020-08-24" @default.
• W3050368757 creator A5013645251 @default.
• W3050368757 creator A5044132025 @default.
• W3050368757 creator A5065398707 @default.
• W3050368757 date "2020-08-17" @default.
• W3050368757 modified "2023-10-12" @default.
• W3050368757 title "HARC as an open-shell strategy to bypass oxidative addition in Ullmann–Goldberg couplings" @default.
• W3050368757 cites W180766444 @default.
• W3050368757 cites W1969487950 @default.
• W3050368757 cites W1970373050 @default.
• W3050368757 cites W1970957276 @default.
• W3050368757 cites W1988593604 @default.
• W3050368757 cites W1989292538 @default.
• W3050368757 cites W2004263788 @default.
• W3050368757 cites W2012630489 @default.
• W3050368757 cites W2020079633 @default.
• W3050368757 cites W2048683089 @default.
• W3050368757 cites W2050722234 @default.
• W3050368757 cites W2060620110 @default.
• W3050368757 cites W2060912642 @default.
• W3050368757 cites W2061974050 @default.
• W3050368757 cites W2062691108 @default.
• W3050368757 cites W2076845909 @default.
• W3050368757 cites W2083790594 @default.
• W3050368757 cites W2164944877 @default.
• W3050368757 cites W2235285708 @default.
• W3050368757 cites W2282022820 @default.
• W3050368757 cites W2413897695 @default.
• W3050368757 cites W2525864328 @default.
• W3050368757 cites W2528694815 @default.
• W3050368757 cites W2530596944 @default.
• W3050368757 cites W2614282336 @default.
• W3050368757 cites W2732615433 @default.
• W3050368757 cites W2771745129 @default.
• W3050368757 cites W2789366878 @default.
• W3050368757 cites W2795832693 @default.
• W3050368757 cites W2807247089 @default.
• W3050368757 cites W2811285632 @default.
• W3050368757 cites W2937653869 @default.
• W3050368757 cites W2948327457 @default.
• W3050368757 cites W2950621155 @default.
• W3050368757 cites W2987805001 @default.
• W3050368757 cites W2998381153 @default.
• W3050368757 cites W3012553782 @default.
• W3050368757 cites W3013757683 @default.
• W3050368757 cites W3023129460 @default.
• W3050368757 doi "https://doi.org/10.1073/pnas.2011831117" @default.
• W3050368757 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7474632" @default.
• W3050368757 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32817531" @default.
• W3050368757 hasPublicationYear "2020" @default.
• W3050368757 type Work @default.
• W3050368757 sameAs 3050368757 @default.
• W3050368757 citedByCount "28" @default.
• W3050368757 countsByYear W30503687572020 @default.
• W3050368757 countsByYear W30503687572021 @default.
• W3050368757 countsByYear W30503687572022 @default.
• W3050368757 countsByYear W30503687572023 @default.
• W3050368757 crossrefType "journal-article" @default.
• W3050368757 hasAuthorship W3050368757A5013645251 @default.
• W3050368757 hasAuthorship W3050368757A5044132025 @default.
• W3050368757 hasAuthorship W3050368757A5065398707 @default.
• W3050368757 hasBestOaLocation W30503687571 @default.
• W3050368757 hasConcept C111368507 @default.
• W3050368757 hasConcept C127313418 @default.
• W3050368757 hasConcept C139066938 @default.
• W3050368757 hasConcept C161790260 @default.
• W3050368757 hasConcept C171560689 @default.
• W3050368757 hasConcept C178790620 @default.
• W3050368757 hasConcept C185592680 @default.
• W3050368757 hasConcept C201194858 @default.
• W3050368757 hasConcept C21951064 @default.
• W3050368757 hasConcept C2777289219 @default.
• W3050368757 hasConcept C2780263894 @default.
• W3050368757 hasConcept C2781076698 @default.
• W3050368757 hasConcept C535685238 @default.
• W3050368757 hasConcept C544778455 @default.
• W3050368757 hasConcept C55493867 @default.
• W3050368757 hasConcept C57600042 @default.
• W3050368757 hasConcept C71240020 @default.
• W3050368757 hasConcept C75473681 @default.
• W3050368757 hasConcept C83155894 @default.
• W3050368757 hasConcept C94882840 @default.
• W3050368757 hasConceptScore W3050368757C111368507 @default.
• W3050368757 hasConceptScore W3050368757C127313418 @default.
• W3050368757 hasConceptScore W3050368757C139066938 @default.
• W3050368757 hasConceptScore W3050368757C161790260 @default.
• W3050368757 hasConceptScore W3050368757C171560689 @default.
• W3050368757 hasConceptScore W3050368757C178790620 @default.
• W3050368757 hasConceptScore W3050368757C185592680 @default.
• W3050368757 hasConceptScore W3050368757C201194858 @default.
• W3050368757 hasConceptScore W3050368757C21951064 @default.
• W3050368757 hasConceptScore W3050368757C2777289219 @default.
• W3050368757 hasConceptScore W3050368757C2780263894 @default.
• W3050368757 hasConceptScore W3050368757C2781076698 @default.
• W3050368757 hasConceptScore W3050368757C535685238 @default.
• W3050368757 hasConceptScore W3050368757C544778455 @default.
• W3050368757 hasConceptScore W3050368757C55493867 @default.

• next