FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3145996834> ?p ?o ?g. }

• W3145996834 endingPage "4497" @default.
• W3145996834 startingPage "4486" @default.
• W3145996834 abstract "It is highly desirable to develop all-pH-compatible hydrogen evolution reaction (HER) electrocatalysts that can be used universally in a variety of different electrolyzers and operated in different pH conditions, i.e., acid, alkaline, microbial, chlor-alkali, etc. So far, two-dimensional layered MoS2 and Mo-based carbon materials have been regarded as promising pH-universal HER electrocatalysts. 2H-MoS2 as a naturally occurring and thermodynamically favorable phase, yet still suffers from poor HER activity in neutral and alkaline electrolytes. Herein, a hybrid electrocatalyst, i.e., 2H-MoS2/N-doped mesoporous graphene, rich in interfacial Mo–pyridinic N coordination is fabricated. The optimized hybrid catalyst delivers long-term durability and outstanding HER activity with overpotentials of 110, 145, and 142 mV at 10 mA cm–2 in acidic, alkaline, and phosphate buffered solutions (PBS) media, respectively, outperforming most of the previously reported MoS2-based catalysts. Theoretical and experimental results demonstrate that the interfacial pyridinic N has a higher tendency to bond with Mo atoms than pyrrolic and graphitic N, and the edge-Mo coordinated with pyridinic N could serve as HER active sites. DFT calculations further reveal that Mo–pyridinic N coordination modifies the charge density of edge-Mo, in turn optimizing the hydrogen absorption energy and facilitating water dissociation, and thereby significantly promoting the intrinsic catalytic activity for the pH-universal HER process." @default.
• W3145996834 created "2021-04-13" @default.
• W3145996834 creator A5001302481 @default.
• W3145996834 creator A5011251664 @default.
• W3145996834 creator A5035286998 @default.
• W3145996834 creator A5043686313 @default.
• W3145996834 creator A5049550458 @default.
• W3145996834 creator A5057811115 @default.
• W3145996834 creator A5063361441 @default.
• W3145996834 creator A5065037360 @default.
• W3145996834 creator A5074235217 @default.
• W3145996834 creator A5081819768 @default.
• W3145996834 date "2021-03-29" @default.
• W3145996834 modified "2023-10-09" @default.
• W3145996834 title "Activating Edge-Mo of 2H-MoS₂ <i>via</i> Coordination with Pyridinic N–C for pH-Universal Hydrogen Evolution Electrocatalysis" @default.
• W3145996834 cites W1139314269 @default.
• W3145996834 cites W1970127494 @default.
• W3145996834 cites W1991229278 @default.
• W3145996834 cites W2002721385 @default.
• W3145996834 cites W2007395042 @default.
• W3145996834 cites W2079105963 @default.
• W3145996834 cites W2083222334 @default.
• W3145996834 cites W2117262972 @default.
• W3145996834 cites W2122427541 @default.
• W3145996834 cites W2133795748 @default.
• W3145996834 cites W2171034745 @default.
• W3145996834 cites W2220596051 @default.
• W3145996834 cites W2222171010 @default.
• W3145996834 cites W2271655480 @default.
• W3145996834 cites W2291673245 @default.
• W3145996834 cites W2292082013 @default.
• W3145996834 cites W2317359288 @default.
• W3145996834 cites W2330613123 @default.
• W3145996834 cites W2332325213 @default.
• W3145996834 cites W2344113634 @default.
• W3145996834 cites W2364175558 @default.
• W3145996834 cites W2461202500 @default.
• W3145996834 cites W2484058627 @default.
• W3145996834 cites W2552196946 @default.
• W3145996834 cites W2566150112 @default.
• W3145996834 cites W2570266091 @default.
• W3145996834 cites W2573377826 @default.
• W3145996834 cites W2589587002 @default.
• W3145996834 cites W2614282509 @default.
• W3145996834 cites W2757489855 @default.
• W3145996834 cites W2765596766 @default.
• W3145996834 cites W2783341085 @default.
• W3145996834 cites W2790174388 @default.
• W3145996834 cites W2791662045 @default.
• W3145996834 cites W2802118659 @default.
• W3145996834 cites W2802758949 @default.
• W3145996834 cites W2806349454 @default.
• W3145996834 cites W2844245918 @default.
• W3145996834 cites W2883369579 @default.
• W3145996834 cites W2885063588 @default.
• W3145996834 cites W2888447136 @default.
• W3145996834 cites W2890278085 @default.
• W3145996834 cites W2891469069 @default.
• W3145996834 cites W2900022033 @default.
• W3145996834 cites W2900436737 @default.
• W3145996834 cites W2901787622 @default.
• W3145996834 cites W2904195942 @default.
• W3145996834 cites W2911731767 @default.
• W3145996834 cites W2921214404 @default.
• W3145996834 cites W2922261481 @default.
• W3145996834 cites W2924989184 @default.
• W3145996834 cites W2947058635 @default.
• W3145996834 cites W2964735803 @default.
• W3145996834 cites W2971573744 @default.
• W3145996834 cites W2986593618 @default.
• W3145996834 cites W3040134019 @default.
• W3145996834 cites W4248677023 @default.
• W3145996834 doi "https://doi.org/10.1021/acscatal.0c04415" @default.
• W3145996834 hasPublicationYear "2021" @default.
• W3145996834 type Work @default.
• W3145996834 sameAs 3145996834 @default.
• W3145996834 citedByCount "59" @default.
• W3145996834 countsByYear W31459968342021 @default.
• W3145996834 countsByYear W31459968342022 @default.
• W3145996834 countsByYear W31459968342023 @default.
• W3145996834 crossrefType "journal-article" @default.
• W3145996834 hasAuthorship W3145996834A5001302481 @default.
• W3145996834 hasAuthorship W3145996834A5011251664 @default.
• W3145996834 hasAuthorship W3145996834A5035286998 @default.
• W3145996834 hasAuthorship W3145996834A5043686313 @default.
• W3145996834 hasAuthorship W3145996834A5049550458 @default.
• W3145996834 hasAuthorship W3145996834A5057811115 @default.
• W3145996834 hasAuthorship W3145996834A5063361441 @default.
• W3145996834 hasAuthorship W3145996834A5065037360 @default.
• W3145996834 hasAuthorship W3145996834A5074235217 @default.
• W3145996834 hasAuthorship W3145996834A5081819768 @default.
• W3145996834 hasConcept C102931765 @default.
• W3145996834 hasConcept C127413603 @default.
• W3145996834 hasConcept C147789679 @default.
• W3145996834 hasConcept C161790260 @default.
• W3145996834 hasConcept C171250308 @default.
• W3145996834 hasConcept C17525397 @default.
• W3145996834 hasConcept C178790620 @default.

• next