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• W3146030911 endingPage "12747" @default.
• W3146030911 startingPage "12739" @default.
• W3146030911 abstract "A product study of the reactions of (E/Z)-1,2,3,3,3-pentafluoropropene ((E/Z)-CF3CF[double bond, length as m-dash]CHF) and hexafluoroisobutylene ((CF3)2C[double bond, length as m-dash]CH2) initiated by Cl atoms were developed at 298 ± 2 K and atmospheric pressure. The experiments were carried out in a 1080 L quartz-glass environmental chamber coupled via in situ FTIR spectroscopy to monitor the reactants and products. The main products observed and their yields were as follows: CF3C(O)F (106 ± 9)% with HC(O)F (100 ± 8)% as a co-product for (E/Z)-CF3CF[double bond, length as m-dash]CHF, and CF3C(O)CF3 (94 ± 5)% with HC(O)Cl (90 ± 7)% as a co-product for (CF3)2C[double bond, length as m-dash]CH2. Atmospheric implications of the end-product degradation are assessed in terms of their impact on ecosystems to help environmental policymakers consider HFOs as acceptable replacements." @default.
• W3146030911 created "2021-04-13" @default.
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• W3146030911 date "2021-01-01" @default.
• W3146030911 modified "2023-09-30" @default.
• W3146030911 title "FTIR product study of the Cl-initiated oxidation products of CFC replacements: (<i>E</i>/<i>Z</i>)-1,2,3,3,3-pentafluoropropene and hexafluoroisobutylene" @default.
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• W3146030911 doi "https://doi.org/10.1039/d1ra00283j" @default.
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