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• W3182023897 abstract "Self-assembled complexes utilizing the ditopic dative bond acceptor 1,3-diboronic acid with catechol and complementary U-shaped donors in the form of 1,8-dipyridylnaphthalenes (1,8-bis(4-pyridyl)naphthalene (DPN), 1,8-bis(4-ethylenylpyridyl)naphthalene (DEPN), and 1,8-bis(4-ethynylpyridyl)naphthalene (DAPN)) yielded discrete two-component structures. The assemblies exhibit “plug-in-socket” geometries. DFT calculations are consistent with the donor pyridyl and acceptor catecholate being electron poor and rich, respectively. The assemblies pack via π–π interactions and support the inclusion of a solvent (i.e., DPN, DAPN). The materials may form a basis for the design of complex B-based structures (e.g., supramolecular dyads)." @default.
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• W3182023897 date "2021-07-13" @default.
• W3182023897 modified "2023-10-16" @default.
• W3182023897 title "Self-Assembly of Diboronic Esters with U-Shaped Bipyridines: “Plug-in-Socket” Assemblies" @default.
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• W3182023897 doi "https://doi.org/10.1021/acs.cgd.1c00382" @default.
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