FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4248011036> ?p ?o ?g. }

• W4248011036 abstract "Abstract Carbon monoxide is a versatile ligand as it forms compounds with both transition metals and main group elements. Transition d metals of electronic configuration d n (0 < n < 10) form the most numerous class of these compounds, although recent progress has been made in expanding the area of existence toward main group, lanthanide (4f) and actinide (5f) metals. The most extensively studied series of carbonyl derivatives have the general formula [M(CO) n ] m , with n representing the coordination number of the central metal atom M, and m being the nuclearity of the system. In these compounds, the central metal atom is in the zero oxidation state. Starting from readily available inorganic derivatives in a positive oxidation state, the synthesis of these compounds normally requires a reducing agent capable of acting in the presence of carbon monoxide: in fact, only nickel metal, as a finely divided activated powder, is reactive toward CO leading to the corresponding derivative Ni(CO) 4 . The selection of the reducing agent varies as a function of the position of the metal M within the periodic table. There is a general trend of an increase in the nuclearity m toward the end of the transition d series, the nuclearity being related to the bonding arrangements of the CO ligand, which may act as terminal, doubly bridging or triply bridging. Metal carbonyls are characterized by IR‐active vibrations around 2000 cm −1 associated with the carbonyl groups. Vibrational spectra in solution give important information about: (a) the electronic distribution within the M–CO bond in terminally bonded carbonyl groups; (b) the molecular structure associated with the number of bands observed; (c) the type of bonding in dinuclear or polynuclear compounds. X‐ray diffraction data have been extensively used in order to define the molecular structure in the solid state. The metal–CO combinations span a wide range of oxidation states, derivatives being known for oxidation states from +III to −IV. Metal carbonyls undergo three types of reaction: (a) substitution of the carbonyl groups, whereby the oxidation state of the central metal atom remains unchanged, (b) oxidation, and (c) reduction. Carbonyl derivatives of early‐ and late transition metals present specific bonding and spectroscopic properties. Concerning the transition elements of groups 6–9, the M–CO bond dissociation enthalpy increases down the group, and is normally greater than the metal–metal bond enthalpy, the latter being estimated from the heat of atomization. From a mechanistic viewpoint, substitution and redox reactions have been studied extensively. A special case of substitution is the migratory carbonyl insertion, by which an M–R bond to a carbyl group R is converted by CO into the M–(CO)R sequence." @default.
• W4248011036 created "2022-05-12" @default.
• W4248011036 creator A5005009184 @default.
• W4248011036 date "2005-09-07" @default.
• W4248011036 modified "2023-10-17" @default.
• W4248011036 title "Carbonyl Complexes of the Transition Metals" @default.
• W4248011036 cites W1431893018 @default.
• W4248011036 cites W1478042268 @default.
• W4248011036 cites W1506494900 @default.
• W4248011036 cites W1531284485 @default.
• W4248011036 cites W1557507391 @default.
• W4248011036 cites W1569020913 @default.
• W4248011036 cites W1623960843 @default.
• W4248011036 cites W167788655 @default.
• W4248011036 cites W1965863520 @default.
• W4248011036 cites W1969519126 @default.
• W4248011036 cites W1970249970 @default.
• W4248011036 cites W1972394856 @default.
• W4248011036 cites W1973200209 @default.
• W4248011036 cites W1981731846 @default.
• W4248011036 cites W1982527976 @default.
• W4248011036 cites W1983998009 @default.
• W4248011036 cites W1987825301 @default.
• W4248011036 cites W1989206042 @default.
• W4248011036 cites W1989916957 @default.
• W4248011036 cites W1990790557 @default.
• W4248011036 cites W1996551682 @default.
• W4248011036 cites W2000374272 @default.
• W4248011036 cites W2000537049 @default.
• W4248011036 cites W2002944904 @default.
• W4248011036 cites W2003405028 @default.
• W4248011036 cites W2004636773 @default.
• W4248011036 cites W2013123253 @default.
• W4248011036 cites W2014593593 @default.
• W4248011036 cites W2014815611 @default.
• W4248011036 cites W2018085659 @default.
• W4248011036 cites W2018465890 @default.
• W4248011036 cites W2020057371 @default.
• W4248011036 cites W2022960655 @default.
• W4248011036 cites W2026250635 @default.
• W4248011036 cites W2035277985 @default.
• W4248011036 cites W2036433994 @default.
• W4248011036 cites W2037682587 @default.
• W4248011036 cites W2038477054 @default.
• W4248011036 cites W2038970394 @default.
• W4248011036 cites W2039425528 @default.
• W4248011036 cites W2041244046 @default.
• W4248011036 cites W2042849830 @default.
• W4248011036 cites W2044477877 @default.
• W4248011036 cites W2050735721 @default.
• W4248011036 cites W2052313940 @default.
• W4248011036 cites W2053416331 @default.
• W4248011036 cites W2055204279 @default.
• W4248011036 cites W2057893874 @default.
• W4248011036 cites W2066043395 @default.
• W4248011036 cites W2066847471 @default.
• W4248011036 cites W2068068639 @default.
• W4248011036 cites W2068487764 @default.
• W4248011036 cites W2068877344 @default.
• W4248011036 cites W2073171681 @default.
• W4248011036 cites W2075339673 @default.
• W4248011036 cites W2076514684 @default.
• W4248011036 cites W2078431099 @default.
• W4248011036 cites W2078730613 @default.
• W4248011036 cites W2080599920 @default.
• W4248011036 cites W2081717219 @default.
• W4248011036 cites W2083206403 @default.
• W4248011036 cites W2083381933 @default.
• W4248011036 cites W2086598547 @default.
• W4248011036 cites W2088587793 @default.
• W4248011036 cites W2089514183 @default.
• W4248011036 cites W2092011216 @default.
• W4248011036 cites W2094678107 @default.
• W4248011036 cites W2094883987 @default.
• W4248011036 cites W2097854129 @default.
• W4248011036 cites W2124673660 @default.
• W4248011036 cites W2132126850 @default.
• W4248011036 cites W2148238597 @default.
• W4248011036 cites W2156315175 @default.
• W4248011036 cites W2165431882 @default.
• W4248011036 cites W2189759159 @default.
• W4248011036 cites W224706799 @default.
• W4248011036 cites W2318052982 @default.
• W4248011036 cites W2326147046 @default.
• W4248011036 cites W2949536233 @default.
• W4248011036 cites W2949810181 @default.
• W4248011036 cites W2950936581 @default.
• W4248011036 cites W2951209239 @default.
• W4248011036 cites W2951364664 @default.
• W4248011036 cites W2952767366 @default.
• W4248011036 cites W3022853711 @default.
• W4248011036 cites W37839289 @default.
• W4248011036 cites W4235876493 @default.
• W4248011036 cites W4247233624 @default.
• W4248011036 cites W951120177 @default.
• W4248011036 cites W279310738 @default.
• W4248011036 doi "https://doi.org/10.1002/0470862106.ia037" @default.
• W4248011036 hasPublicationYear "2005" @default.
• W4248011036 type Work @default.
• W4248011036 citedByCount "2" @default.

• next