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- W4297910366 abstract "Abstract Starting with the stoichiometric and highly homogeneous gel-precursor, single-phase metastable melilite La 2 Ga 3 O 7.5 , as the end-member of solid solution La 1+ x Sr 1− x Ga 3 O 7+ x /2 (0≼ x ≼1), has been synthesized by solid-state reaction at 700 °C for 2 h via a kinetically favorable mechanism and characterized by X-ray diffraction (XRD), Raman, X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), AC impedance spectroscopy, etc. It has been revealed that the as-synthesized melilite La 2 Ga 3 O 7.5 shows an orthorhombic symmetry with crystal cell parameters a = 11.4690(1) Å, b = 11.2825(4) Å, and c = 10.3735(4) Å, while has more Raman active modes than LaSrGa 3 O 7 with a tetragonal structure, which was also synthesized under the same conditions for comparison, but tends to slowly decompose into perovskite LaGaO 3 and Ga 2 O 3 when annealed at 700 °C for over 20 h driven by its meta-stability. Moreover, the metastable La 2 Ga 3 O 7.5 shows a higher XPS binding energy for the excess oxide ions in the crystal structure than those at normal lattice sites. Its intrinsic grain oxide ion conductivity can reach as high as 0.04 and 0.51 mS·cm −1 at 550 and 700 °C, respectively, characterized by a simple Arrhenius relationship ln( σT )—1/ T with invariable activation energy, E a = 1.22 eV, over the temperature range from 300 to 700 °C, along with an apparent grain boundary conductivity that is about double that from the grains thanks to the clean grain boundaries. This paper provides a new strategic approach to the synthesis of complex oxides that may be of high performance but are difficultly achieved by the conventional ceramic method at high temperatures." @default.
- W4297910366 created "2022-10-01" @default.
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- W4297910366 date "2022-09-24" @default.
- W4297910366 modified "2023-09-26" @default.
- W4297910366 title "Sol—gel approach to low-temperature synthesis of single-phase metastable La2Ga3O7.5 melilite with enhanced grain-boundary oxide ionic conductivity via a kinetically favorable mechanism" @default.
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- W4297910366 doi "https://doi.org/10.1007/s40145-022-0635-x" @default.
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