Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308156988> ?p ?o ?g. }
- W4308156988 endingPage "126412" @default.
- W4308156988 startingPage "126412" @default.
- W4308156988 abstract "Although considerable progress has been made in the hydrogenation of CO2 to light olefins through the modified Fischer-Tropsch synthesis route (CO2-FTS), the design of catalysts with high selectivity and stability is still a challenge. Herein, a simple, highly dispersed and scalable Fe/C-400 catalyst was prepared by in-situ pyrolysis using pomelo peel (PP) as carbon source, and was first used in CO2 hydrogenation to light olefins. This catalyst exhibited a high space time yield of light olefins (48.3 μmolCO2·gFe−1·s−1), and the light olefins selectivity and O/P were 63.0% and 9.0, respectively. More surprisingly, no obvious deactivation was observed within 200 h. A series of characterization techniques such as TEM, TG-MS, FTIR, XPS, H2-TPR and 57Fe Mössbauer spectrum showed that the naturally abundant oxygen-containing functional groups in PP support could impart metal-support interactions that enhance the dispersion of iron species. The modulation of the catalyst phase composition was achieved by simply varying the residual amount of oxygen-containing functional groups to impart different metal-support interactions. The catalysts prepared at lower pyrolysis temperatures retained more oxygen-containing functional groups and therefore had stronger metal-support interactions, which facilitated the formation of more active phases. Overall, this newly developed catalyst realized the high activity and high stability production of CO2 hydrogenation to light olefins, providing a cost-effective and sustainable way for its industrial application." @default.
- W4308156988 created "2022-11-08" @default.
- W4308156988 creator A5008032475 @default.
- W4308156988 creator A5023922518 @default.
- W4308156988 creator A5026984704 @default.
- W4308156988 creator A5032470217 @default.
- W4308156988 creator A5045739126 @default.
- W4308156988 creator A5049204344 @default.
- W4308156988 creator A5061107952 @default.
- W4308156988 creator A5069961963 @default.
- W4308156988 creator A5077027194 @default.
- W4308156988 creator A5078244008 @default.
- W4308156988 date "2023-02-01" @default.
- W4308156988 modified "2023-10-06" @default.
- W4308156988 title "In situ synthesis of highly dispersed Fe/C catalysts with pomelo peel as carbon source in CO2 hydrogenation to light olefins" @default.
- W4308156988 cites W1813070442 @default.
- W4308156988 cites W1870760280 @default.
- W4308156988 cites W1987300299 @default.
- W4308156988 cites W1997845317 @default.
- W4308156988 cites W2066001471 @default.
- W4308156988 cites W2143717100 @default.
- W4308156988 cites W2480932326 @default.
- W4308156988 cites W2571238523 @default.
- W4308156988 cites W2611869399 @default.
- W4308156988 cites W2752661218 @default.
- W4308156988 cites W2810091962 @default.
- W4308156988 cites W2810202639 @default.
- W4308156988 cites W2895212771 @default.
- W4308156988 cites W2897319235 @default.
- W4308156988 cites W2934139628 @default.
- W4308156988 cites W2939195482 @default.
- W4308156988 cites W2944372659 @default.
- W4308156988 cites W2963065636 @default.
- W4308156988 cites W2992717940 @default.
- W4308156988 cites W3024631293 @default.
- W4308156988 cites W3038184686 @default.
- W4308156988 cites W3044670117 @default.
- W4308156988 cites W3089857180 @default.
- W4308156988 cites W3092035842 @default.
- W4308156988 cites W3112963134 @default.
- W4308156988 cites W3166324470 @default.
- W4308156988 cites W3194716506 @default.
- W4308156988 cites W3196408718 @default.
- W4308156988 cites W4205438698 @default.
- W4308156988 cites W4210549081 @default.
- W4308156988 cites W4245029202 @default.
- W4308156988 cites W4280642688 @default.
- W4308156988 cites W4281610611 @default.
- W4308156988 doi "https://doi.org/10.1016/j.fuel.2022.126412" @default.
- W4308156988 hasPublicationYear "2023" @default.
- W4308156988 type Work @default.
- W4308156988 citedByCount "3" @default.
- W4308156988 countsByYear W43081569882023 @default.
- W4308156988 crossrefType "journal-article" @default.
- W4308156988 hasAuthorship W4308156988A5008032475 @default.
- W4308156988 hasAuthorship W4308156988A5023922518 @default.
- W4308156988 hasAuthorship W4308156988A5026984704 @default.
- W4308156988 hasAuthorship W4308156988A5032470217 @default.
- W4308156988 hasAuthorship W4308156988A5045739126 @default.
- W4308156988 hasAuthorship W4308156988A5049204344 @default.
- W4308156988 hasAuthorship W4308156988A5061107952 @default.
- W4308156988 hasAuthorship W4308156988A5069961963 @default.
- W4308156988 hasAuthorship W4308156988A5077027194 @default.
- W4308156988 hasAuthorship W4308156988A5078244008 @default.
- W4308156988 hasConcept C104779481 @default.
- W4308156988 hasConcept C118792377 @default.
- W4308156988 hasConcept C120665830 @default.
- W4308156988 hasConcept C121332964 @default.
- W4308156988 hasConcept C127413603 @default.
- W4308156988 hasConcept C134121241 @default.
- W4308156988 hasConcept C140205800 @default.
- W4308156988 hasConcept C159985019 @default.
- W4308156988 hasConcept C160892712 @default.
- W4308156988 hasConcept C161790260 @default.
- W4308156988 hasConcept C175708663 @default.
- W4308156988 hasConcept C177562468 @default.
- W4308156988 hasConcept C178790620 @default.
- W4308156988 hasConcept C185592680 @default.
- W4308156988 hasConcept C191897082 @default.
- W4308156988 hasConcept C192562407 @default.
- W4308156988 hasConcept C36759035 @default.
- W4308156988 hasConcept C42360764 @default.
- W4308156988 hasConcept C540031477 @default.
- W4308156988 hasConcept C544153396 @default.
- W4308156988 hasConcept C62192006 @default.
- W4308156988 hasConceptScore W4308156988C104779481 @default.
- W4308156988 hasConceptScore W4308156988C118792377 @default.
- W4308156988 hasConceptScore W4308156988C120665830 @default.
- W4308156988 hasConceptScore W4308156988C121332964 @default.
- W4308156988 hasConceptScore W4308156988C127413603 @default.
- W4308156988 hasConceptScore W4308156988C134121241 @default.
- W4308156988 hasConceptScore W4308156988C140205800 @default.
- W4308156988 hasConceptScore W4308156988C159985019 @default.
- W4308156988 hasConceptScore W4308156988C160892712 @default.
- W4308156988 hasConceptScore W4308156988C161790260 @default.
- W4308156988 hasConceptScore W4308156988C175708663 @default.
- W4308156988 hasConceptScore W4308156988C177562468 @default.
- W4308156988 hasConceptScore W4308156988C178790620 @default.