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• W4310361622 endingPage "16654" @default.
• W4310361622 startingPage "16644" @default.
• W4310361622 abstract "A strategy for photochemical oxidative cleavage of the aminomethylene group at the C2 position of indole was developed to synthesize C2-carbonyl indoles. The reaction was initiated by the photochemical oxidation of N1, followed by a water-assisted concerted H-shift by abstracting hydrogen from aminomethylene. Bromopyridine was discovered to play dual roles as an oxidant for the regeneration of photocatalysts and as an accelerant for the single-electron transfer process." @default.
• W4310361622 created "2022-12-09" @default.
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• W4310361622 date "2022-11-29" @default.
• W4310361622 modified "2023-10-11" @default.
• W4310361622 title "Synthesis of C2-Carbonyl Indoles via Visible Light-Induced Oxidative Cleavage of an Aminomethylene Group" @default.
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• W4310361622 doi "https://doi.org/10.1021/acs.joc.2c02292" @default.
• W4310361622 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36445203" @default.
• W4310361622 hasPublicationYear "2022" @default.
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