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- W4313829742 abstract "Abstract Elemental selenium (Se 0 ) nanomaterials undergo allotropic transition from thermodynamically‐unstable to more stable phases. This process is significantly different when Se 0 nanoparticles (NPs) are produced via physico‐chemical and biological pathways. While the allotropic transition of physico‐chemically synthesized Se 0 is fast (minutes to hours), the biogenic Se 0 takes months to complete. The biopolymer layer covering biogenic Se 0 NPs might be the main factor controlling this retardation, but this still remains an open question. Phylogenetically‐diverse bacteria reduce selenium oxyanions to red amorphous Se 0 allotrope, which has low market value. Then, red Se 0 undergoes allotropic transition to trigonal (metallic grey) allotrope, the end product having important industrial applications (e.g. semiconductors, alloys). Is it not yet clear whether biogenic Se 0 presents any biological function, or it is mainly a detoxification and respiratory by‐product. The better understanding of this transition would benefit the recovery of Se 0 NPs from secondary resources and its targeted utilization with respect to each allotropic stage. This review article presents and critically discusses the main physico‐chemical methods and biosynthetic pathways of Se 0 (bio)mineralization. In addition, the article proposes a conceptual model for the resource recovery potential of trigonal selenium nanomaterials in the context of circular economy." @default.
- W4313829742 created "2023-01-09" @default.
- W4313829742 creator A5040985855 @default.
- W4313829742 creator A5052900200 @default.
- W4313829742 creator A5056452959 @default.
- W4313829742 creator A5077882613 @default.
- W4313829742 date "2023-01-09" @default.
- W4313829742 modified "2023-10-02" @default.
- W4313829742 title "Allotropy of selenium nanoparticles: Colourful transition, synthesis, and biotechnological applications" @default.
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