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- W1001121608 abstract "The title complex [Cu2(bipy)2(Hpht)2Cl](Hpht) (bipy = 2,2'-bipyridine, H2pht=o-phthalic acid) has been synthesized in the NaOH aqueous solution of CuCl2, Gd(NO3)3, bipy and H2pht, and its crystal structure was determined by single-crystal X-ray diffraction method. It crystallizes in triclinic, space group PI, C44H31ClCu2N4O12, Mr = 970.26, a= 8.175(2), b = 16.254(4), c= 16.946(4)A°,α= 62.966(6), β= 84.833(8), γ= 84.348(8)°, V = 1993.4(8) A°^3 Z = 2, Dc = 1.616g/cm^3, F(000) = 988 and μ= 1.207 mm^-1. The final R = 0.0429 and wR = 0.0843 for 5682 observed reflections with I > 2σ(I). Each copper(Ⅱ) atom displays a distorted square-pyramidal geometry with two nitrogen atoms of one chelate 2,2'-bipy molecule, two oxygen atoms from two different bridging carboxylate groups of Hpht^- and one bridging chloride atom occupying the apical position. The two copper(Ⅱ) atoms are connected by aμ2-Cl atom and two bridging Hpht^- ligands in a syn-syn coordination mode to form an isolated dinuclear unit. The molecular structure is extended to a one-dimensional wavy chain through hydrogen bonds. The title complex exhibits blue fluorescent emission at 443 nm (λex= 372 nm) in the solid state at room temperature." @default.
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- W1001121608 date "2005-01-01" @default.
- W1001121608 modified "2023-09-23" @default.
- W1001121608 title "Synthesis, Structure and Fluorescence of a Copper（II） Complex [Cu2（bipy）2（Hpht）2Cl]（Hpht）（bipy = 2,2＇-Bipyridine, H2pht = o-Phthalic Acid）" @default.
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