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- W1001337524 abstract "为了更好指导N2O5硝解3，7-二硝基-1，3，5，7-四氮杂双环[3．3．1]壬烷（DPT）制备奥克托今（HMX）的生产，研究了DPT在N2O5／HNO3和N2O5／CH2CI2两种体系中的硝解产物，采用柱层析从硝解产物中分离得到了两个副产物，并进行了结构表征，确证其为：N，N’-二羟甲基硝胺和1，9-二硝酰氧基-2，4，6，8-四硝基-2，4，6，8-四氮杂壬烷。N2O5硝解DPT，当体系中溶解有硝酸铵时，N2O5浓度低时主要起硝化作用反应生成HMX，N2O5浓度高时主要起酯化作用反应生成直链产物；当体系中没有硝酸铵（或硝酸铵不溶解）时，N2O5主要起酯化作用也生成直链产物。" @default.
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- W1001337524 date "2012-01-01" @default.
- W1001337524 modified "2023-09-23" @default.
- W1001337524 title "3,7-二硝基-1,3,5,7-四氮杂双环［3.3.1］壬烷的硝解副产物及硝解机理" @default.
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