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- W1001558803 abstract "Publisher Summary The chemistry of compounds having boron groups connected to transition metals has expanded very rapidly in the past few years. The complexes in the iron group have significance in the history of organometallic and boron chemistry. The first reported examples of π-bonded carborane-transition metal compounds were the 1, 2-dicarbollyl analogs of ferrocene and the ferricinium ion discovered by Hawthorne and co-workers. The crystal and molecular structure of the cyclopentadienyl complex obtained by X-ray diffraction afforded the first confirmation of the sandwich bonding of the carborane ligand to the iron atom. The positions of substitution are as far as possible from the carbon atoms. If this reaction is electrophilic in nature, this result pinpoints the region of highest electron density in this type of molecule. The syntheses of the carbollide-transition metal complexes thus far reported are based on three general routes closely related to the preparative methods used for the dicarbollyl sandwich compounds." @default.
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- W1001558803 date "1970-01-01" @default.
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- W1001558803 title "Transition Metal-Carborane Complexes" @default.
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- W1001558803 doi "https://doi.org/10.1016/s0065-3055(08)60634-6" @default.
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