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- W100180861 abstract "Publisher Summary According to the modern definition of acids and bases, “an acid is a species having a tendency to lose a proton, and a base is a species having a tendency to add on a proton.” This chapter emphasizes that the uses of modern acid-base theory in physical organic chemistry are manifold and of critical importance. It is responsible for the understanding of the whole subject of acid-base catalysis, with its many applications, for example, in ester hydrolysis, tautomerism (and pseudoacidity), and in the general theory of the kinetics of organic reactions. The complex and biologically important field of protein solution physical chemistry is dominated by the dipolar ion (zwitterion) nature of the amino acids and peptides, and by the fact that in the molecule of a given protein there are many basic and acidic groupings, characteristic in number and arrangement for the given protein. The correlation of the strengths of the organic acidic and basic compounds with their molecular structure is of major importance in the elucidation of the nature of electronic valency bonding forces and their molecular environmental variations." @default.
- W100180861 created "2016-06-24" @default.
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- W100180861 date "1964-01-01" @default.
- W100180861 modified "2023-09-27" @default.
- W100180861 title "Modern Physico-Chemical Views on Acids and Bases and Their Application to Carbon Compounds" @default.
- W100180861 doi "https://doi.org/10.1016/b978-044453345-6.50458-2" @default.
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