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• W1004828813 abstract "Vapor-liquid phase equilibrium data of tertpentanol in carbon dioxide were measured at temperatures of 313.4, 323.4, 333.5 and 343.5 K and in the pressure range of 4.56―11.44 MPa. The phase equilibium apparatus used in the work was a variable-volume high-pressure cell. The experimental data were reasonably correlated with Peng-Robinson equation of state(PR-EOS) together with van der Waals-2 two-parameter mixing rules. Henry's Law constants and partial molar volumes of CO2 at infinite dilution were estimated with Krichevsky-Kasarnovsky equa- tion, and Henry's Law constants increase with increasing temperature, however, partial molar volumes of CO2 at in- finite dilution are negative whose magnitudes decrease with temperature. Partial molar volumes of CO2 and tertpen- tanol in liquid phase at equilibrium were calculated. Keywords Carbon dioxide; Tertpentanol; Phase equilibrium; Henry's Law constant; Partial molar volume Article ID 1005-9040(2011)-04-678-05" @default.
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• W1004828813 date "2011-01-01" @default.
• W1004828813 modified "2023-09-23" @default.
• W1004828813 title "Vapor-liquid Phase Equilibria for CO_2+Tertpentanol Binary System at Elevated Pressures" @default.
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